Mesoporous silicas modified with dioxomolybdenum(VI) complexes: Synthesis and catalysis

European Journal of Inorganic Chemistry

Volumn , Issue 10, 2000, Pages 2263-2270

  Ferreira, Paula ^a   Goncalves, Isabel S ^a   Kiihn, Fritz E ^a   Lopes, André D ^a   Martins, Manuel A ^a   Pillinger, Martyn ^a   Pina, Anabela ^b   Rocha, Joâo ^a,c   Rornao, Carlos C ^b   Santos, Ana M ^b   Santos, Teresa M ^a   Valente, Anabela A ^b  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^c INSTITUTO DE TECNOLOGIA QUÍMICA E BIOLÓGICA   (Portugal)

Author keywords

Epoxidations; MCM materials; Mesoporosity; Molybdenum; Oxo complexes; Supported catalysts

Indexed keywords

CATALYSTS; MAGIC ANGLE SPINNING; MESOPOROUS MATERIALS; MOLECULAR SIEVES; MOLYBDENUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; SILICA; X RAY DIFFRACTION;

DIOXOMOLYBDENUM; DIRECT GRAFTING; IR-SPECTROSCOPY; MCM MATERIAL; MCM-48 MOLECULAR SIEVES; MESOPOROSITY; MESOPOROUS SILICAS; N 2 ADSORPTION; ORDERED MESOPORES; OXO COMPLEXES;

SYNTHESIS (CHEMICAL);

CYCLOALKENE; MOLYBDENUM COMPLEX; NITROGEN; SILICON DIOXIDE; TERT BUTYL HYDROPEROXIDE;

ABSORPTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; EPOXIDATION; FINITE ELEMENT ANALYSIS; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POROSITY; REACTION ANALYSIS; SYNTHESIS; X RAY POWDER DIFFRACTION;

EID: 0033775142     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200010)2000:10<2263::AID-EJIC2263>3.0.CO;2-U     Document Type: Article

References (42)

1. [1a] Halcon (J. Kollar), U.S. Pat. 3,351,635, 1967;
2. Chein. Abstr. 1968, 68, 2094. -
3. [1b] Halcon (J. Kollar), U.S. Pat. 3,350,422, 1967;
4. Chein. Abstr. 1968, 68, 278.
5. [2a] R A. Sheldon, Aspects of Homogeneous Catalysis (Ed.: R. Ugo), vol. 4, Reidel, Dordrecht, The Netherlands, 1981, p. 1.
6. [2b] R. A. Sheldon, J. Mol Catal. 1980, 7, 107-126.
7. [3a] R A Sheldon, I. W. C. E. Arends, H. E. B. tempers, Catalysis Today 1998, 41, 387-407.
8. - '3bl R. A. Sheldon, M. Wallau, I. W. C. E. Arends, U. Schuchardt, Acc. Chein. Res. 1998, 31, 485-493.
9. W R. Murugavel, H. W. Roesky, Augen: Chem. Int. Ed. Engl. 1997, 36, 477-479.
10. [5a] M Taramasso, G. Perego, B. Notar! (Enichem), US Pat. 4 410 501, 1981;
11. Chein. Abstr. 1981, 95, 137.
12. [5b] B. Notari, Stud. Surf. Sci. Catal 1987, 37, 413.
13. [6a] j ßlasco, M. A. Camblor, A. Corma, J. Pérez-Pariente, J. Am. Chem. Soc. 1993, 115, 11806-11813.
14. [6b] M. A. Camblor, M. Constantin!, A. Corma, L. Gilbert, P. Esteve, A. Martinez, S. Valencia, Chem. Commun. 1996, 1339-1340.
15. A. Corma, M. T. Navarro, J. Pérez-Pariente, J. Chem. Soc., Chem. Commun. 199-4, 147-148.
16. [8a] T. Maschmeyer, F. Rev, G. Sankar, J. M. Thomas, Nature 1995, 378, 159-162.
17. [8b] L. Marchese, E. Gianotti, V. Dellarocca, T. Maschmeyer, F. Rey, S. Coluccia, J. M. Thomas, Phys. Chem. Chem. Phys. 1999, 1, 585-592.
18. [8c] P. Ferreira, I. S. Gonçalves, F. E. Kühn, M. Pillineer, J. Rocha, A. M. Santos, A. Thursfield, Enr. J. Inorg. Chem., 2000, 551-557.
19. [9a] C. T Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Nature 1992, 559, 710-712.
20. [9b] J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Oison, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenker, J. Am. Chem. Soc. 1992,114, 10834-10843.
21. [10a] S. O'Brien, J. Tudor, S. Barlow, M. J. Drewit. S. J. Heyes, D. O'Hare, Chem. Commun. 1997, 641-642.
22. [10b] P. Ferreira, I. S. Gonçalves, F. Mosselmans, M. Pillinger, J. Rocha, A. Thursfield, Eur. J. Inorg. Citent. 2000, 97-102.
23. V. Alfredsson, M. Anderson, Chem. Mater. 1996, 8, 1141.
24. [12a] P S Raghavan, V. Ramaswamy, T. T. Upadhya, A. Sudalai, A. V. Ramaswamy, S. Sivasanker, J. Mol. Catal. A: Chem. 1997, 722, 75-80.
25. [12b] P. S. Raghavan, M. P. Vinod, J. Mol. Catal. A: Chem. 1998, 135, 47-53.
26. I. J. Shannon, T. Maschmeyer, R. D. Oldroyd, G. Sankar, J. M. Thomas, H. Pernot, J. -P. Balikdjian, M. Che, J. Chem. Soc., Faraday Trans. 1998, 94, 1495-1499.
27. A. Corma, A. Fuerte, M. Iglesias, F. Sänchez, J. Mol. Catal. A: Chem. 1996, 707, 225-234.
28. [15a] F. E. Kuhn, E. Herdtweck, J. J. Haider, W. A. Herrmann, I. S. Gonçalves, A. D. Lopes, C. C. Romào, J. Organomet. Chem. 1999, 583, 3-10.
29. [15b] F. E. Kühn, A. D. Lopes, A. M. Santos, E. Herdtweck, 1 J. Haider, C. C. Romào, A. G. Santos, J. Mol. Catal. A: Clicm., 2000, 757, 147-160.
30. R. Schmidt, M. Stöcker, E. Hansen, D. Akporiaye, O. H. Ellestad, Microporous Mater. 1995, 3, 443.
31. S. J. Grcgg, K. S. W. Sing, Adsorption, Surface Area and Porosity, 2nd ed., Academic Press, London, 1982.
32. M. D. Alba, A. Becerro, J. Klinowski, J. Chem. Soc., Faraday Trans. 1996, 92, 849.
33. A. A. Romero, M. D. Alba, W. Zhou, J. Klinowski, J. Phys. Chem. B 1997, 707, 5294.
34. D. Brunei, A. Cauvel, F. Fajula, F. DiRenzo, Stud. Surf. Sci. Catal. 1995, 97, 173.
35. R. D. Oldroyd, J. M. Thomas, T. Maschmeyer, P. A. MacFaul, D. W. Snelgrove, K. U. Insold, D. D. M. Wayner, Angew. Chem. Int. Ed Engl. 1996, 35, 2787-2790.
36. R. A. Sheldon, J. A. Van Doom, J. Catal. 1973, 31, 427.
37. A. Corma, U. Diaz, V. Fernes, J. L. Jordâ, M. Domine, F. Rey, Chem. Commun. 1999, 779-780.
38. [24a] A Monger, p. Schiith, Q. Huo, D. Kumar, D. Margolese, R. S. Maxwell, G. D. Stucky, M. Krishnamurty, P. PetrofT, A. Firouz, M. Janicke, B. F. Chmelka, Science 1993, 261, 1299.
39. [24b] J. Xu, Z. Luan, H. He, W. Zhou, L. Kevan, Chem. Mater. 1998, 10, 3690.
40. R. Colton, I. B. Tomkins, Aust. J. Chem. 1965, 75, 447.
41. [26a] M. Minelli, j. H. Enemark, R. T. C. Brownlee, M. J. O'Connor, A. G. Wedd, Coord. Chem. Rev. 1985, 68, 169.
42. [26b] F. E. Kühn, A. M. Santos, A. D. Lopes, I. S. Gonçalves, E. Herdtweck, C. C. Romào, J. Mol. Catal. A: Client., in press.