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Binap = 2,2′-bis(diphenylphosphino)-2, 2′-binaphthyl. (a) Miyashita, A.; Yasuda, A.; Takaya, H.; Toriumi, K.; Ito, T.; Souchi, T.; Noyori, R. J. Am. Chem. Soc. 1980, 102, 7932.
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Recently, van Leeuwen et al. prepared a series of triarylbisphosphines of large bite angles and applied them to transition metalcatalyzed reactions, (a) Kranenburg, M.; van der Burgt, Y. E. M.; Kamer, P. C. J.; van Leeuwen, P. W. N. M.; Goubitz, K.; Fraanje, J. Organometallics 1995, 14, 3081.
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Bennett et al. obtained a small amount of dpbp as a reductive elimination product from orthometalated complexes. See: (a) Bennett, M. A.; Bhargava, S. K.; Griffiths, K. D.; Robertson, G. B. Angew. Chem., Int. Ed. Engl. 1987, 26, 260.
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