Binuclear nickel(II) complexes based on bridging oxalate and pseudohalides as peripheral ligands: Synthesis, crystal structure, DFT calculations and magnetic properties of [{Ni(X)(dien)}2(μ-ox)]·nH2O complexes (X = N3-, NCS-, n = 0; NCO-, n = 1)

European Journal of Inorganic Chemistry

Volumn , Issue 12, 2000, Pages 2541-2547

  Muga, Iñaki ^a   Gutiérrez Zorrilla, Juan M ^a   Vitoria, Pablo ^a   Luque, Antonio ^a   Insausti, Maite ^a   Román, Pascual ^a   Lloret, Francesc ^b  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Binuclear complexes; Density functional calculations; Magnetic properties; Nickel; Structure elucidation

Indexed keywords

ATOMS; CHELATION; CRYSTAL ATOMIC STRUCTURE; DENSITY FUNCTIONAL THEORY; MAGNETIC SUSCEPTIBILITY; NICKEL; NICKEL COMPOUNDS; OXALIC ACID; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); LIGANDS;

BINUCLEAR COMPLEXES; CRYSTALS STRUCTURES; DENSITY-FUNCTIONAL CALCULATIONS; DISPLACEMENT REACTIONS; NI 2; NICKEL ATOMS; NITROGEN ATOM; PSEUDO HALIDE; STRUCTURE ELUCIDATION;

LIGANDS; DENSITY FUNCTIONAL THEORY;

HALIDE; LIGAND; NICKEL COMPLEX; OXALIC ACID; WATER;

ARTICLE; CALCULATION; CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY; MAGNETISM; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 0033675115     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200012)2000:12<2541::AID-EJIC2541>3.0.CO;2-O     Document Type: Article

References (70)

1. [1a] D. Gatteschi, O. Khan, J. S. Miller, F. Palacio, Magnetic Molecular Materials, Kluwer, Dordrecht, 1991.
2. [1b] Inorganic Materials (Eds.: Q. W. Bruce, D. O'Hare), Wiley, Chichester, 1992.
3. [1c] O. Khan, Molecular Magnetism, VCH, New York, 1993.
4. [2a] P. J. Hay, J. C. Thibeault, R. Hoffmann, J. Am. Chem. Soc. 1975, 97, 4884.
5. [2b] S. Alvarez, M. Julve, M. Verdaguer, Inorg. Chem. 1990, 29, 4500.
6. [2c] P. Román, C. Guzmán-Miralles, A. Luque, J. I. Beitia, J. Cano, F. Lloret, M. Julve, S. Alvarez, Inorg. Chem. 1996, 35, 3741.
7. [2d] J. Cano, E. Ruiz, P. Alemany, F. Lloret, S. Alvarez, J. Chem. Soc., Dalton Trans. 1999, 1669.
8. [3a] N. F. Curtis, I. R. N. McCormick, T. N. Waters, J. Chem. Soc., Dalton Trans. 1973, 1537.
9. [3b] M. Julve, M. Verdaguer, O. Kahn, A. Gleizes, M. Philoche-Levisalles, Inorg. Chem. 1983, 22, 368.
10. [3c] J. Sletten, Acta Chem. Scand. Ser. A 1983, 37, 569.
11. [3d] M. Julve, M. Verdaguer, A. Gleizes, M. Philoche-Levisalles, O. Kahn, Inorg. Chem. 1984, 23, 3808.
12. [3e] M. Julve, J. Faus, M. Verdaguer, A. Gleizes, J. Am. Chem. Soc. 1984, 106, 8306.
13. [3f] A. Bencini, A. C. Fabretti, C. Zanchini, P. Zannini, Inorg. Chem. 1987, 26, 1445.
14. [3g] J. A. Real, J. Borras, X. Solans, M. Font-Altaba, Transition Met. Chem. 1987, 12, 254.
15. [3h] L. Soto, J. Garcia, E. Escriva, J.-P. Legros, J.-P. Tuchagues, F. Dahan, A. Fuertes, Inorg. Chem. 1989, 28, 3378.
16. [3i] I. Castro, J. Faus, M. Julve, M. Mollar, A. Monge, E. Gutiérrez-Puebla, Inorg. Chim. Acta 1989, 161, 97.
17. [3j] I. Castro, J. Faus, M. Julve, M. C. Munoz, W. Diaz, X. Solans, Inorg. Chim. Acta 1991, 179, 59.
18. [3k] I. Castro, J. Faus, M. Julve, A. Gleizes, J. Chem. Soc., Dalton Trans. 1991, 1937.
19. [3l] L. S. Tuero, J. Garcia-Lozano, E. E. Monto, M. B. Borja, F. Dahan, J.-P. Tuchagues, J.-P. Legros, J. Chem. Soc., Dalton Trans. 1991, 2619.
20. [3m] A. Gleizes, M. Julve, M. Verdaguer, J. A. Real, J. Faus, X. Solans, J. Chem. Soc., Dalton Trans. 1992, 3209.
21. [3n] C. George, A. Purdy, Acta Crystallogr., Sect. C 1992, 48, 155.
22. [3o] P. E. Kruger, K. S. Murray, E. R. T. Tienkink, Z. Kristallogr. 1994, 209, 624.
23. [3p] J. Li, J. Sun, P. Chen, X. Wu, Cryst. Res. and Technol. 1995, 30, 353.
24. [3q] S. Warzeska, R. Kramer, Chem. Ber. 1995, 128, 115.
25. [3r] R. Vicente, A. Escuer, J. Ferretjans, H. Stoeckli-Evans, X. Solans, M. Font-Bardia, J. Chem. Soc., Dalton Trans. 1997, 167.
26. [3s] M. K. Saha, S. Sen, P. Kundu, T. Gupta, V. Gramlich, S. Mitra, Z. Naturforsch., Teil B 1998, 53, 1281.
27. [3t] Z. Smekal, Z. Travnicek, M. Nadvornik, Z. Sindelar, R. Klicka, J. Marek, Collect. Czech. Chem. Commun. 1998, 63, 783.
28. [3u] O. Castillo, I. Muga, A. Luque, J. M. Gutiérrez-Zorrilla, J. Sertucha, P. Vitoria, P. Román, Polyhedron 1999, 18, 1235.
29. [4a] D. M. Duggan, E. K. Barefield, D. N. Hendrickson, Inorg. Chem. 1973, 12, 985.
30. [4b] J. Kopf, U. Behrens, M. Kastner, G. Klar, J. Inorg. Nucl. Chem. 1977, 39, 889.
31. [4c] A. R. Davis, F. W. B. Einstein, A. C. Willis, Acta Crystallogr., Sect. B 1982, 38, 443.
32. [4d] N. W. Alcock, P. Moore, H. A. A. Omar, Acta Crystallogr., Sect. C 1987, 43, 2074.
33. [4e] H.-F. Klein, T. Wiemer, M.-J. Menu, M. Dartiguenave, Y. Dartiguenave, Inorg. Chim. Acta 1988, 154, 21.
34. [4f] L. P. Battaglia, A. Bianchi, A. B. Corradi, E. Garcia-España, M. Micheloni, M. Julve, Inorg. Chem. 1988, 27, 4174.
35. [4g] J. Ribas, M. Monfort, C. Díaz, X. Solans, Anal. Quim. 1988, 84, 186.
36. [4h] M. I. Arriortua, R. Cortes, T. Rojo, J. Via, X. Solans, Eur. J. Solid State Inorg. Chem. 1989, 26, 91.
37. [4i] A. Bencini, A. Bianchi, P. Paoli, E. Garcia-España, M. Julve, V. Marcelino, J. Chem. Soc., Dalton Trans. 1990, 2213.
38. [4j] A. Bencini, A. Bianchi, E. Garcia-España, Y. Jeannin, M. Julve, V. Marcelino, M. Philoche-Levisalles, Inorg. Chem. 1990, 29, 963.
39. [4k] K. Yamada, Y. Fukuda, T. Kawamoto, Y. Kushi, W. Mori, K. Unoura, Bull. Chem. Soc. Jpn. 1993, 66, 2758.
40. [4l] A. Escuer, R. Vicente, J. Ribas, J. Jaud, B. Raynaud, Inorg. Chim. Acta 1994, 216, 139.
41. [4m] A. Escuer, R. Vicente, M. S. El Fallah, J. Jaud, Inorg. Chim. Acta 1995, 232, 151.
42. [4n] M. Hagiwara, K. Kobayashi, T. Chihara, J. Phys. Soc. Jpn. 1997, 66, 1702.
43. [4o] Z. Travnicek, Z. Smekal, J. Marek, Z. Kristallogr. 1997, 212, 123.
44. [4p] I. Castro, M. L. Calatayud, J. Sletten, F. Lloret, M. Julve, J. Chem. Soc., Dalton Trans. 1997, 811.
45. [5a] M. G. B. Drew, G. W. A. Fowles, D. F. Lewis, J. Chem. Soc. D. 1969, 876.
46. [5b] N. F. Curtis, I. R. N. McCormick, T. N. Waters, J. Chem. Soc., Dalton Trans. 1973, 1537.
47. [5c] A. E. Shvelashvili, L. M. Chanturia, N. I. Pirtskhalava, M. G. Tavberidze, A. I. Kvitashvili, B. M. Shchedrin, Soob. Akad. Nauk Gruz. SSR 1974, 75, 597.
48. [5d] A. E. Shvelashvili, M. A. Porai-Koshits, A. I. Kvitashvili, B. M. Shchedrin, Zh. Strukt. Khim. 1974, 15, 310.
49. [5e] I. F. Bourshteyn, A. E. Shvelashvili, B. M. Shchedrin, Kristallokhim. Neorg. Soedin 1976, 163.
50. [5f] F. Bottomley, I. J. B. Lin, P. S. White, J. Organomet. Chem. 1981, 212, 341.
51. [5g] A. Penicaud, P. Batail, K. Bechgaard, J. Sala-Pala, Synthetic Metals 1988, 22, 201.
52. [5h] M. Ohba, H. Tamaki, N. Matsumoto, H. Okawa, Inorg. Chem. 1993, 32, 5385.
53. [5i] R. Cortés, M. K. Urtiaga, L. Lezama, M. I. Arriortua, T. Rojo, Inorg. Chem. 1994, 33, 829.
54. [5j] M. I. Khan, Yuan-Da Chang, Qin Chen, J. Salta, Y.-S. Lee, C. J. O'Connor, J. Zubieta, Inorg. Chem. 1994, 33, 6340.
55. [5k] J. Glerup, P. A. Goodson, D. J. Hodgson, K. Michelsen, Inorg. Chem. 1995, 34, 6255.
56. [5l] J. Salta, C. J. O'Connor, S. Li, J. Zubieta, Inorg. Chim. Acta 1996, 250, 303.
57. [5m] M. Andruh, R. Melanson, C. V. Stager, F. D. Rochon, Inorg. Chim. Acta 1996, 251, 309.
58. [5n] M. Feist, S. Troyanov, E. Kemnitz, Inorg. Chem. 1996, 35, 3067.
59. [5o] K. Heinze, G. Huttner, L. Zsolnai, A. Jacobi, P. Schober, Eur. J. Chem. 1997, 3, 732.
60. [5p] Xinjian Lei, Maoyu Shang, T. P. Fehlner, Organometallics 1997, 16, 5289.
61. [5q] Li-Min Zheng, H. W. Schmalle, S. Ferlay, S. Decurtins, Acta Crystallogr., Sect. C 1998, 54, 1435.
62. [5r] V. M. Masters, C. A. Sharrad, P. V. Bernhardt, L. R. Gahan, B. Moubaraki, K. S. Murray, J. Chem. Soc., Dalton Trans. 1998, 413.
63. Refs. [2c], [4m].
64. I. Muga, J. M. Gutiérrez-Zorrilla, A. Luque, P. Román, F. Lloret, Inorg. Chem. 1997, 36, 743.
65. V. Rodríguez, J. M. Gutiérrez-Zorrilla, P. Vitoria, A. Luque, P. Román, M. Martínez-Ripoll, Inorg. Chim. Acta 1999, 290, 57.
66. G. De Munno, M. Julve, F. Lloret, A. Derory, J. Chem. Soc., Dalton Trans. 1993, 1179.
67. International Tables for X-ray Crystallography, Vol. 4, Kynoch, Birmingham, UK, 1974, pp 55, 99, and 149.
68. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. Garcia-Grande, R. O. Gould, J. M. M. Smits, C. Smykalla, The DIRDIF92 program system, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1992.
69. J. M. Stewart, P. A. Machin, C. W. Dickinson, H. L. Ammon, H. Heck, H. Flack, The X-ray 76 system, Technical report tr-446, Computer Science Center, University of Maryland, College Park, 1976.
70. J. Rodríguez-Carvajal, Physica B 1992, 192, 55.