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24
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0344595571
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note
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a values of around 4 and 10, respectively, the acidity is still dictated by the organic acid.
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-
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26
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0345026577
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note
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9
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27
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0344595570
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note
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olig).
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30
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0344164019
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note
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17
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31
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0001404067
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Bartl, J.; Steenken, S.; Mayr, H. J. Am. Chem. Soc. 1991, 113, 7710-7716.
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32
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0004200260
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Brooks/Cole: Pacific Grove
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McMurry, J. Organic Chemistry, 2nd ed.; Brooks/Cole: Pacific Grove, 1988; p 596. o-HBA or acidic impurities can serve as the acid catalyst.
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Organic Chemistry, 2nd Ed.
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McMurry, J.1
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33
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0344595568
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note
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Remarkably, next to 2,2-dimethylchroman (9), another, yet unknown product, was observed when tert-butyl alcohol was used as a solvent together with methanol, 2-propanol, and benzyl alcohol.
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34
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0345457692
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note
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In phenol, 2,2′- and 2,4′-DHD (11 and 15) are identified by comparison with spectra in the NIST GC-MS library. In anisole, 2,2′- and 2,4′-HMD (12 and 16) are identified based on GC (retention times) and GC-MS analysis.
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37
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0344164018
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note
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-1.
-
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-
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40
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0345457689
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note
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In these experiments, the mass balance amounted to 43-47% of the initial o-HBA concentration. In all experiments ca. 2% of the dimer of o-HBA was found and ca. 3% of an unknown, high-boiling product.
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41
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0344164017
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note
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-1.
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42
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0345612011
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Mayr, H.1
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52
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0344164016
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note
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-1, respectively.
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53
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0345026575
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To be published
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By using differential functional theory (DFT) calculated values from: Santoro, D.; Korth, H. G.; Mulder, P. To be published.
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Santoro, D.1
Korth, H.G.2
Mulder, P.3
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55
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0001601579
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57
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0344164015
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note
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The authors wish to thank an anonymous reviewer for insisting that our data are also consistent with o-QM reactivity.
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58
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0029291339
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