Major and trace elements associated with colloids in organic-rich river waters: Ultrafiltration of natural and spiked solutions

Chemical Geology

Volumn 160, Issue 1-2, 1999, Pages 63-80

  Dupré, Bernard ^a   Viers, Jerome ^a   Dandurand, Jean Louis ^a   Polve, Mireille ^a   Bénézeth, Pascale ^b   Vervier, Philippe ^c   Braun, Jean Jacques ^d  

^a CNRS   (France)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

^c CESAC Centre d'Ecologie des Systèmes Aquatiques Continentaux   (France)

^d Institut de Recherche pour le Developpement Cameroon   (Cameroon)

Author keywords

Colloids; Complexation; Isotope; Organic matter; Rare Earth Elements; Stability constant; Strontium; Ultrafiltration

Indexed keywords

ORGANIC COMPOUND; RIVER; ULTRAFILTRATION;

COLLOID; ORGANIC MATTER; RIVER WATER; TRACE ELEMENT; ULTRAFILTRATION;

EID: 0033614918     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(99)00060-1     Document Type: Article

References (72)

1. Akinfiev, N.N., 1986. «Balance»; IBM computer code for calculating mineral aqueous solution-gas equilibria. Geochemistry 6, 882-890, in Russian.
2. 238U in the Kalix River and in the Baltic Sea. Geochim. Cosmochim. Acta 62, 382-392.
3. Baes, C.F., Mesmer, R.E., 1976. The Hydrolysis of Cations. Wiley, New York, 489 pp.
4. Bénézeth, P., Castet, S., Dandurand, J.L., Gout, R., Schott, J., 1994. Experimental study of aluminium-acetate complexing between 60 and 200°C. Geochim. Cosmochim. Acta 58, 4561-4571.
5. Bessoles, B., 1980. Géologie de l'Afrique, Vol 2. La chaîne panafricaine, zone mobile d'Afrique centrale et zone mobile soudanaise. Mem. BRGM 92, 398 pp.
6. Bresnahan, W.T., Grant, C.L., Weber, J.H., 1978. Stability constants for the complexation of copper (II) ions with water and soil fulvic acids measured by an ion selective electrode. Anal. Chem. 50, 1675-1679.
7. Browne, B.A., Driscoll, C.T., 1993. PH-dependent binding of aluminum by a fulvic acid. Environ. Sci. Technol. 27, 915-922.
8. Buesseler, K.O., Bauer, J., Chen, R., Eglinton, T., Gustafsson, O., Landing, W., Mopper, K., Moran, S.B., Santschi, P., VernonClark, R., Wells, M., 1996. Sampling marine colloids using cross-flow filtration: an overview and results from an intercomparison study. In: Buffle, J., van Leeuwen, H.P. (Eds.), Environmental Particles, Vol. 1. Lewis, Boca Raton, 171-230.
9. Buffle, J., Van Leeuwen, H.P., 1992. Environmental Particles, Vol. 1. Lewis Publishers.
10. Buffle, J., Greter, F.L., Werner, H., 1977. Measurement of complexation properties of humic and fulvic acids in natural waters with lead and copper ion-selective electrodes. Anal. Chem. 49, 216-222.
11. Burba, P., Shkinev, V., Spivakov, B.Y., 1995. On-line fractionation and characterisation of aquatic humic substances by means of sequential-stage ultrafiltration. J. Anal. Chem. 351, 74-82.
12. Cabaniss, S.E., Shuman, M.S., 1988. Copper binding by dissolved organic matter: Suwannee River fulvic acid equilibria. Geochim. Cosmochim. Acta 52, 185-193.
13. Castet, S., Dandurand, J.L., Schott, J., Gout, R., 1993. Boehmite solubility and aqueous aluminium speciation in hydrothermal solutions (90-350°C): experimental study and modeling. Geochim. Cosmochim. Acta 57, 4869-4883.
14. Cronan, C.S., Aiken, G.R., 1985. Chemistry and transport of soluble humic substances in forested watersheds of the Adirondack Park New York. Geochim. Cosmochim. Acta 49, 1697-1705.
15. Czerwinski, K.R., Buckau, G., Scherbaum, F., Kim, J.I., 1994. Complexation of the uranyl ion with aquatic humic acid. Radiochim. Acta 65, 111-119.
16. Dai, M., Martin, J.-M., 1995. First data on trace metal level and behaviour in two major Arctic river-estuarine systems (Ob and Yenisey) and in the adjacent Kara Sea, Russia. Earth Planet. Sci. Lett. 131, 127-141.
17. Dai, M., Martin, J.-M., Cauwet, G., 1995. The significant role of colloids in the transport and transformation of organic carbon and associated trace metals (Cd, Cu and Ni) in the Rhône delta (France). Mar. Chem. 51, 159-175.
18. 3 solubilities (25 to 150°C), and La-acetate complexing (25 to 80°C). Chem. Geol. 151, 349-372.
19. Diakonov, I., 1995. Etude expérimentale de la complexation de l'aluminium avec l'ion sodium et de la spéciation du gallium et du fer (III) dans les solutions naturelles. PhD Thèse de l'Université Paul-Sabatier, Toulouse, 166 pp.
20. Ephraim, J.H., Marinsky, J.A., 1990. Ultrafiltration as a technique for studying metal-humate interactions: studies with iron and copper. Anal. Chim. Acta 232, 171-180.
21. Ephraim, J.H., Xu, H., 1989. The binding of cadmium by an aquatic fulvic acid: a comparison of ultrafiltration with ion-exchange distribution and ion-selective electrode techniques. Sci. Total Environ. 81/82, 625-634.
22. Eyrolle, F., Benedetti, M.F., Benaim, J.-Y., Fevrier, D., 1996. The distributions of colloidal and dissolved organic carbon, major elements and trace elements in small tropical catchments. Geochim. Cosmochim. Acta 60, 3643-3656.
23. Eyrolle, F., Fevrier, D., Benaim, J.-Y., 1993. Etude par D.P.A.S.V. de l'aptitude de la matière organique colloïdale à fixer et à transporter les métaux: exemples de bassins versants en zone tropicale. Environ. Technol. 14, 701-717.
24. Frimmel, F.H., 1988. Bonding and transport of metals by humic substances. In: Frimmel, F.H., Christman, R.F. (Eds.), Humic substances and their role in the environment. Wiley-Interscience, 165-178.
25. Fukushima, M., Nakayasu, K., Tanaka, S., Nakamura, H., 1995. Chromium(III) binding abilities of humic acids. Anal. Chim. Acta 317, 195-206.
26. Gustafsson, O., Buesseler, K.O., Gschwend, P.M., 1996. On the integrity of cross-flow filtration for collecting marine organic colloids. Mar. Chem. 55, 93-111.
27. Hays, M.D., Ryan, D.J., Pennell, S., Milenkovic, L.V., 1996. Data treatments for relating metal-ion binding to fulvic acid as measured by fluorescence spectroscopy. In: Gaffney, J.S., Marley, N.A., Clark, S.B. (Eds.), Humic and Fulvic Acids. Isolation, Structure and Environmental Role. Am. Chem. Soc., 108-123.
28. Hering, J.G., Morel, F.F., 1988. Humic acid complexation of calcium and copper. Environ. Sci. Technol. 22, 1234-1237.
29. Hoffmann, M.R., Yost, E.C., Eisenreich, S.J., Maier, W.J., 1981. Characterization of soluble and colloidal-phase metal complexes in river water by ultrafiltration. A mass balance approach. Environ. Sci. Technol. 15, 655-661.
30. Horowitz, A.J., Lum, K.R., Garbarino, J.R., Hall, G.E.M., Lemieux, C., Demas, C.R., 1996. The effect of membrane filtration on dissolved trace element concentrations. Water, Air and Soil Poll. 90, 281-294.
31. Hummel, W., Glaus, M., Van Loon, L.R., 1995. Binding of radionuclides by humic substances: the 'Conservative Roof approach. In: Proceedings of an NEA Workshop, 14-16 September 1994, Bad Zurzach, Switzerland, OECD documents, ISBN no. 92-94, 251-262.
32. Kinniburgh, D.G., Milne, C.J., Benedetti, M.F., Pinheiro, J.P., Filius, J., Koopal, L.K., Van Riemsdijk, W.H., 1996. Metal ion binding by humic acid: application of the NCA-Donnan model. Environ. Sci. Technol. 30, 1687-1698.
33. Lakshman, S., Mills, R., Patterson, H., Cronan, C., 1993. Apparent differences in binding site distributions and aluminum(III) complexation for three molecular weight fractions of a coniferous soil fulvic acid. Anal. Chim. Acta 282, 101-108.
34. Lambert, J., Buddrus, J., Burba, P., 1995. Evaluation of conditional stability constants of dissolved aluminum/humic substance complexes by means of Al nuclear magnetic resonance. Fresenius J. Anal. Chem. 351, 83-87.
35. Langmuir, D., Herman, J.S., 1980. The mobility of thorium in natural waters at low temperatures. Geochim. Cosmochim. Acta 44, 1753-1766.
36. Liu, Y., Ingle, J.D., 1989. Two-column ion-exchange method for the determination of copper-complexing capacity and conditional stability constants of copper complexes for ligands in natural waters. Talanta 36, 185-192.
37. 2+ by peat and humic acid. Eur. J. Soil Sci. 48, 685-696.
38. Manunza, B., Deiana, S., Maddau, V., Gessa, C., Seeber, R., 1995. Stability constants of metal-humate complexes: titration data analyzed by bimodal gaussian distribution. Soil Sci. Soc. Am. J. 59, 1570-1574.
39. Martel, A.E., Hancock, R.D., 1996. Metal complexes in aqueous solutions. Modern Inorganic Chemistry, 253 pp.
40. Martell, A.E., Smith, R.M., 1977. Critical Stability Constants. Vol. 3. Other Organic Ligands. Plenum.
41. Martin, F., Petit, S., Decarreau, A., Ildefonse, Ph., Grauby, O., Beziat, D., de Parseval, Ph., Noack, Y., 1998. Ga/Al substitutions in synthetic kaolinites and smectites. Clay Minerals 33, 231-241.
42. Mathutu, A.S., Ephraim, J.H., 1993. Calcium binding by fulvic acids studied by an ion selective electrode and an ultrafiltration method. Talanta 4, 521-526.
43. Murphy, E.M., Zachara, J.M., 1995. The role of sorbed humic substances on the distribution of organic and inorganic contaminants in groundwater. Geoderma 67, 103-124.
44. Oliver, B.G., Thurman, E.M., Malcolm, R.L., 1983. The contribution of humic substances to the acidity of colored natural waters. Geochim. Cosmochim. Acta 47, 2031-2035.
45. Olivie-Lauquet, G., 1996. Analyse des transferts solides dans la géosphére tropicale: exemple du bassin versant du Nyong (Cameroun). Thèse de l'Université Paris VII, 203 pp.
46. Olivie-Lauquet, G., Allard, T., Benedetti M., Muller J.P., 1999. Chemical Distribution of Trivalent Iron in Riverine Material from a Tropical Ecosystem: A Quantitative EPR Study. Submitted to Water Res.
47. Olivry, J.C., 1986. Fleuves et rivières du Cameroun. Monographies Hydrologiques ORSTOM No. 9. Ed. MESRESORSTOM, 733 pp.
48. O'Shea, T.A., Mancy, K.H., 1976. Anal. Chem. 48, 1603-1607.
49. Perdue, E.M., Reuter, J.H., Parrish, R.S., 1984. A statistical model of proton binding by humus. Geochim. Cosmochim. Acta 48, 1257-1263.
50. Pham, M.K., Garnier, J.-M., 1998. Distribution of trace elements associated with dissolved compounds (< 0.45 μm-1 nm) in freshwater using coupled (frontal cascade) ultrafiltration and chromatographic separations. Environ. Sci. Technol. 32, 440-449.
51. Porcelli, D., Andersson, P.S., Wasserburg, G.J., Ingri, J., Baskaran, M., 1997. The importance of colloids and mires for the transport of uranium isotopes through the Kalix river watershed and Baltic Sea. Geochim. Cosmochim. Acta 61, 4095-4113.
52. Pott, D.B., Alberts, J.J., Elzerman, A.W., 1985. The influence of pH on the binding capacity and conditional stability constants of aluminium and naturally-occurring organic matter. Chem. Geol. 48, 293-304.
53. Preston, C.M., 1996. Applications of NMR to soil organic matter analysis: history and prospects. Soil Science 161, 144-166.
54. 2+, measured by dialysis titration: a model based on soil fulvic acid aggregation. Can. J. Chem. 60, 1-5.
55. 13C-NMR spectroscopy and comparison with a maleic oligomer of known structure. Geoderma 58, 233-244.
56. Saar, R.A., Weber, J.H., 1980. Lead(II) complexation by fulvic acid: how it differs from fulvic acid complexation of copper(II) and cadmium(II). Geochim. Cosmochim. Acta 44, 1381-1384.
57. Senesi, N., 1990. Molecular and quantitative aspects of the chemistry of fulvic acid and its interactions with metal ions and organic chemicals: Part I. The electron spin resonance approach. Anal. Chim. acta 232, 51-75.
58. Senesi, N., Bocian, D.F., Sposito, G., 1985a. Electron spin resonance investigation of copper (II) complexation by soil fulvic acid. Soil Sci. Soc. Am. J. 49, 114-119.
59. Senesi, N., Bocian, D.F., Sposito, G., 1985b. Electron spin resonance investigation of copper(II) complexation by fulvic acid extracted from sewage sludge. Soil Sci. Soc. Am. J. 49, 119-126.
60. Shin, H.S., Lee, B.H., Choi, J.G., Moon, H., 1995. Complexation of soil humic acid with trivalent Curium and Europium ions: a comparative study. Radiochim. Acta 69, 185-189.
61. Sholkovitz, E.R., 1976. Flocculation of dissolved organic and inorganic matter during the mixing of river water and sea water. Geochim. Cosmochim. Acta 40, 831-845.
62. Sholkovitz, E.R., 1995. The aquatic chemistry of Rare Earth Elements in rivers and estuaries. Aquat. Chem. 1, 1-34.
63. 2+ complexes with humic acids. Soil Sci. Am. J. 40, 665-672.
64. Stevenson, F.J., 1994. Humus Chemistry: Genesis, Composition, Reactions. Wiley, 2nd edn.
65. Stevenson, F.J., Chen, Y., 1991. Stability constants of copper(II)-humate complexes determined by modified potentiometric titration. Soil. Sci. Soc. Am. J. 55, 1586-1591.
66. Stevenson, F.J., Vance, G.F., 1989. Naturally occurring aluminum-organic complexes. In: Sposito, G. (Ed.), The environmental chemistry of aluminum. CRC Press, Boca Raton, FL, 117-146.
67. Thurman, E.M., 1985. Organic Geochemistry of Natural Waters. Nijhoff/junk, Dordrecht, 497 pp.
68. Turner, D.R., Varney, M.S., Whitfield, M., Mantoura, R.F.C., Riley, J.P., 1986. Electrochemical studies of copper and lead complexation by fulvic acid: I. Potentiometric measurements and a critical comparison of metal binding models. Geochim. Cosmochim. Acta 50, 289-297.
69. Vance, G.F., David, M.B., 1991. Chemical characteristics and acidity of soluble organic substances from a northern hardwood forest floor, central Maine, USA. Geochim. Cosmochim. Acta 55, 3611-3625.
70. Viers, J., Dupre, B., Polve, M., Schott, J., Dandurand, J.L., Braun, J.J., 1997. Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon): comparison between organic-poor and organic-rich waters. Chem. Geol. 140, 181-206.
71. 2+ hinging sites in soil humic substances using X-ray absorption spectroscopy. Geochim. Cosmochim. Acta 61, 2211-2221.
72. Xia, K., Bleam, W., Helmke, P.A., 1997b. Studies of the nature of hinging sites of first row transition elements bound to aquatic and soil humic substances using X-ray absorption spectroscopy. Geochim. Cosmochim. Acta 61, 2223-2235.