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Volumn 40, Issue 35, 1999, Pages 6365-6368

A fluorous phase approach to rhodium-catalyzed carbenoid reactions with diazoacetates

Author keywords

Cyclopropanes; Diazo compounds; Perfluoroalkyl compounds; Rhodium and compounds

Indexed keywords

ACETIC ACID DERIVATIVE; AZO COMPOUND; CYCLOPROPANE DERIVATIVE; RHODIUM;

EID: 0033609837     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01332-5     Document Type: Article
Times cited : (37)

References (28)
  • 2
    • 0002586214 scopus 로고
    • Top
    • a) Maas, G. Top. Curr. Chem. 1987, 137, 77. -
    • (1987) Curr. Chem. , vol.137 , pp. 77
    • Maas, G.1
  • 23
    • 1842640868 scopus 로고
    • The use of complex 2a to catalyze C-H insertion of alkoxycarbonylcarbenes into C-H bonds of alkanes was mentioned, but its preparation and properties have not been described
    • The use of complex 2a to catalyze C-H insertion of alkoxycarbonylcarbenes into C-H bonds of alkanes was mentioned, but its preparation and properties have not been described: Demonceau, A.; Noels, A. F.; Hubert, A. J.; Teyssié, P. J. Chem. Soc., Chem. Commun. 1981, 688.
    • (1981) J. Chem. Soc., Chem. Commun. , vol.688
    • Demonceau, A.1    Noels, A.F.2    Hubert, A.J.3    Teyssié, P.4
  • 24
    • 0009580269 scopus 로고    scopus 로고
    • note
    • 3CN ligands and formation of 2a).
  • 25
    • 0009615845 scopus 로고    scopus 로고
    • 2 (4 ml) was added during 8 h with a syringe pump. After an additional time of 4 h the solvent and most of the alkene were removed at 40 °C/500 mbar. The liquid residue was stirred for 15 min with perfluoro(methylcyclohexane) (0.6 ml). After phase separation the dark-green fluorous phase was removed and the liquid residue was distilled at 100°C/ 0.1 mbar to afford 5d
    • 2 (4 ml) was added during 8 h with a syringe pump. After an additional time of 4 h the solvent and most of the alkene were removed at 40 °C/500 mbar. The liquid residue was stirred for 15 min with perfluoro(methylcyclohexane) (0.6 ml). After phase separation the dark-green fluorous phase was removed and the liquid residue was distilled at 100°C/ 0.1 mbar to afford 5d.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.