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T. Munyemana, PhD thesis, University of Louvain la Neuve (Belgium) 1991.
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Munyemana, T.1
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0001700348
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In the fluorination of propargylic alcohols, the only exception appears to be in perfluorinated compounds leading to some fluoro allenes It has been suggested that small amounts of allenes have been obtained also in the fluorination of hydroxyphosphonates
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In the fluorination of propargylic alcohols, the only exception appears to be in perfluorinated compounds leading to some fluoro allenes see : R.E.A. Dear, E.E. Gilbert, J. Org. Chem. 1968, 33, 819-823. It has been suggested that small amounts of allenes have been obtained also in the fluorination of hydroxyphosphonates.
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Dear, R.E.A.1
Gilbert, E.E.2
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28
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0009605388
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3SnH a mixture of 2E (63%), 2Z (23%) and 2′ (13%) was isolated in a similar yield. Furthermore, it is interesting to note that Pd catalysed hydrostannylation gives a 60:40 mixture of 2′ (33% yield) and 2E (22% yield). The stannylcupration gives only decomposition products
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3SnH a mixture of 2E (63%), 2Z (23%) and 2′ (13%) was isolated in a similar yield. Furthermore, it is interesting to note that Pd catalysed hydrostannylation gives a 60:40 mixture of 2′ (33% yield) and 2E (22% yield). The stannylcupration gives only decomposition products.
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29
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0009602008
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note
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22FI.
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34
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0000629440
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L.S. Liebeskind Ed, JAI Press, Greenwich
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T. Jeffery in Advances in Metal-organic Chemistry, L.S. Liebeskind Ed, vol 5, p. 153-260 JAI Press, Greenwich, 1996.
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Jeffery, T.1
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35
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0009602010
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note
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2.
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36
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0009579441
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Preliminary studies indicate that Stille or Suzuki type reactions are possible, but the yields are low (20-30%)
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Preliminary studies indicate that Stille or Suzuki type reactions are possible, but the yields are low (20-30%).
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