Stereoselective backbone modifications of peptides via chelate enolate Claisen rearrangement

Journal of Organic Chemistry

Volumn 64, Issue 13, 1999, Pages 4574-4575

  Kazmaier, Uli ^a   Maier, Sabine ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; AMINO ACID; GLYCINE; LEAD; MANGANESE; PEPTIDE;

AMINO ACID METABOLISM; AMINO ACID SEQUENCE; ANTIMICROBIAL ACTIVITY; ARTICLE; CHELATION; CHIRALITY; ENANTIOMER; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033603455     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9904821     Document Type: Article

References (36)

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28. The crotyl esters were chosen, because they allow the generation of two stereogenic centers in a highly diagtereoselective fashion (95% ds), as determined by HPLC or GC.
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34. HPLC analyses were performed on the corresponding methyl esters using a achiral column (silica gel) and a chiral column (Daicel OD-H) as well.
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