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43
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0342658160
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note
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3SiH (ref 20), however, allowed for a high yield of the deprotected product to be isolated.
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44
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0343964198
-
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note
-
The ability of biaryl 35 to induce α-elimination of HCl from dichloromethane was noted during the growth of a single crystal from an ether/dichloromethane solution. The crystal grown was demonstrated to be hydrochloride of biaryl 35 by single-crystal X-ray analysis.
-
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-
-
50
-
-
0343964197
-
-
note
-
1H NMR signals for methylene protons gave a more complex splitting pattern at 243 K (similar to that of biaryl 28). For biaryl 29 no decoalescence was observed even at 223 K.
-
-
-
-
51
-
-
0343092424
-
-
note
-
3). The effect is more pronounced for naphthyl derivatives 31 and 55 (-0.69 and -0.70 ppm, respectively, relative to 16) than for phenyl analogue 25 (-0.34 ppm).
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-
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0343964193
-
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note
-
X-ray single-crystal structures of biaryl 38 and its N-oxide are almost superimposable, suggesting a high level of across-ring conjugation in the parent molecule 38.
-
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-
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69
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0025164652
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0343964191
-
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note
-
Prepared by an analogous route to that described for the preparation of biaryl 55 via low-yielding (13%) Suzuki cross-coupling of aryl bromide 36 with arylboronic acid 51. Various attempts to accomplish a similar coupling with aryl bromide 41 failed.
-
-
-
-
82
-
-
0343964189
-
-
note
-
Prepared from 1-bromo-3-methoxynaphthalene (ref 45) according to the procedure described for the preparation of arylboronic acid 51.
-
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83
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-
-
0343528365
-
-
note
-
13C NMR, which can be attributed to a small amount of the anhydride formed.
-
-
-
|