Palladium-catalyzed Heck reaction in perfluorinated solvents

Tetrahedron Letters

Volumn 40, Issue 43, 1999, Pages 7683-7686

  Moineau, Johanne ^a   Pozzi, Gianluca ^a,b   Quici, Silvio ^b   Sinou, Denis ^a  

^a UNIVERSITÉ LYON 1   (France)

^b CNR   (Italy)

Author keywords

Heck reactions; Palladium; Perfluorinated ligands; Perfluorinated solvents; Recycling

Indexed keywords

ACRYLIC ACID METHYL ESTER; FLUOROCARBON; IODINE DERIVATIVE; LIGAND; ORGANOMETALLIC COMPOUND; PALLADIUM; PHOSPHINE DERIVATIVE; SOLVENT;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; MOLECULAR INTERACTION;

EID: 0033595846     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01590-7     Document Type: Article

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28. -4 mmol) was stirred in D-100 (2 mL) at room temperature for 0.5 h. A solution of iodobenzene (102 mg, 0.5 mmol), methyl acrylate (54 mg, 0.62 mmol), and triethylamine (43 mg, 1 mmol), in acetonitrile (2 mL) was added. After being stirred at 80°C for 4 h, the reaction mixture was cooled to 0°C, and the acetonitrile phase was separated by simple decantation. For the recycling of the catalyst, another acetonitrile solution of reactants was simply added to the fluorous phase containing the catalyst.