Metal complexes of a tetraazacyclotetradecane bearing highly fluorinated tails: New catalysts for the oxidation of hydrocarbons under fluorous biphasic conditions

Tetrahedron Letters

Volumn 38, Issue 43, 1997, Pages 7605-7608

  Pozzi, Gianluca ^a   Cavazzini, Marco ^a   Quici, Silvio ^a   Fontana, Simonetta ^b  

^a CNR   (Italy)

^b Ausimont SpA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; COMPLEX FORMATION; DRUG SYNTHESIS; OXIDATION; REACTION ANALYSIS;

EID: 0030860898     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01805-4     Document Type: Article

References (21)

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16. 22: C, 26.30; H, 1.36; N, 1.72; F = 59.76. Found: C, 27.03; H, 1.20; N, 1.91; F = 59.28 %.
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19. 2: Co, 1.42. Found: Co = 1.37.
20. Biphasic catalytic oxidation of hydrocarbons is often carried out in the presence of a large excess of substrate, even when a solvent is used. For a recent example see: Battioni, F.; Cardin, E.; Louloudi, M.; Schöllhorn, B.; Spyroulias, G.A.; Mansuy, D.; Traylor, T.G. Chem. Commun., 1996, 2036-2037.
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