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Volumn 119, Issue 31, 1997, Pages 7400-7401

First observation of intramolecular charge-transfer emission from jet-cooled (p-Cyanophenyl)pentamethyldisilane in an isolated molecular condition

Author keywords

[No Author keywords available]

Indexed keywords

SILANE DERIVATIVE;

EID: 0030801117     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971445z     Document Type: Article
Times cited : (31)

References (46)
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    • For recent reviews, see: (a) Rettig, W. Angew. Chem., Int. Ed. Engl. 1986, 25, 971. (b) Bhattacharyya, K.; Chowdhury, M. Chem. Rev. 1993, 93, 507.
    • (1986) Angew. Chem., Int. Ed. Engl. , vol.25 , pp. 971
    • Rettig, W.1
  • 4
    • 4243106516 scopus 로고
    • For recent reviews, see: (a) Rettig, W. Angew. Chem., Int. Ed. Engl. 1986, 25, 971. (b) Bhattacharyya, K.; Chowdhury, M. Chem. Rev. 1993, 93, 507.
    • (1993) Chem. Rev. , vol.93 , pp. 507
    • Bhattacharyya, K.1    Chowdhury, M.2
  • 6
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    • (a) Rotkiewicz, K.; Grellmann, K. H.; Grabowski, Z. R. Chem. Phys. Lett. 1973, 19, 315; 1973, 21, 212.
    • (1973) Chem. Phys. Lett. , vol.21 , pp. 212
  • 10
    • 36549099452 scopus 로고
    • (b) Grassian, V. H.; Warren, J. A.; Bernstein, E. R.; Secor, H. V. J. Chem. Phys. 1989, 90, 3994; 1990, 93, 6910.
    • (1990) J. Chem. Phys. , vol.93 , pp. 6910
  • 34
    • 1842298848 scopus 로고    scopus 로고
    • note
    • 4n,v,w
  • 36
    • 0001698311 scopus 로고
    • (b) Kira, M.; Miyazawa, T.; Sugiyama, H.; Yamaguchi, M.; Sakurai, H. J. Am. Chem. Soc. 1993, 115, 3116. On the basis of the substituent, solvent, and stereoelectronic effects on the absorption and emission spectra of various aryldisilanes, they have proposed the OICT (σπ* orthogonal intramolecular charge transfer) mechanism for stabilization of the ICT state.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 3116
    • Kira, M.1    Miyazawa, T.2    Sugiyama, H.3    Yamaguchi, M.4    Sakurai, H.5
  • 37
    • 37049092162 scopus 로고
    • A different nature of the ICT states of aryldisilanes has been proposed by Shizuka et al., where the disilanyl and a π system are assumed to serve as an acceptor and a donor, respectively, (a) Shizuka, H.; Obuchi, H.; Ishikawa, M.; Kumada, M. J. Chem. Soc., Chem. Commun. 1981, 405.
    • (1981) J. Chem. Soc., Chem. Commun. , pp. 405
    • Shizuka, H.1    Obuchi, H.2    Ishikawa, M.3    Kumada, M.4
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    • 1842333435 scopus 로고    scopus 로고
    • note
    • 6b The preparation procedure of CPDS is also outlined in ref 6b.
  • 44
    • 1842403054 scopus 로고    scopus 로고
    • note
    • Details of their assignments will be published in a forthcoming paper.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.