On the relationship of HO2+RO2 with j(O1D) during the Free Tropospheric Experiment (FREETEX '96) at the Jungfraujoch Observatory(3580 m above sea level) in the Swiss Alps

Journal of Geophysical Research Atmospheres

Volumn 104, Issue D21, 1999, Pages 26913-26925

  Zanis, Prodromos ^a   Monks, Paul S ^b   Schuepbach, Evi ^a   Penkett, Stuart A ^c  

^a UNIVERSITY OF BERN   (Switzerland)

^b UNIVERSITY OF LEICESTER   (United Kingdom)

^c UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; PEROXY RADICAL; PHOTOLYSIS; TROPOSPHERE;

JUNGFRAUJOCH; SWITZERLAND;

EID: 0033589450     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/1999JD900282     Document Type: Article

References (34)

1. 2 and a series of organic peroxy radicals, J. Atmos. Chem., 29, 233-266, 1998.
2. Ayers, G.P., S.A. Penkett, R.W. Gillet, B. Bandy, I.E. Galbally, C.P. Meyer, C.M. Elsworth, S.T. Bentley, and B.W. Forgan, Evidence for photochemical control of ozone concentrations in unpolluted marine air, Nature, 360, 446-449, 1992.
3. Ayers, G.P., H. Granek, and R. Boers, Ozone in the marine boundary layer at Cape Grim: Model simulation, J. Atmos. Chem., 27, 179-195, 1997.
4. Baltensperger, U., H.W. Gäggeler, D.T. Jost, M. Lugauer, M. Schwikowski, and P. Seibert, Aerosol climatology at a high Alpine site Jungfraujoch, Switzerland, J. Geophys. Res., 102, 19,707-19,715, 1997.
5. Cantrell, C.A., and D.H. Stedman, A possible technique for the measurement of atmospheric peroxy radicals, Geophys. Res. Lett., 9, 846-849, 1982.
6. Carpenter, L.J., P.S. Monks, B.J. Bandy, S.A. Penkett, I.E. Galbally, and C.P. Meyer, A study of peroxy radicals and ozone photochemistry at coastal sites in the northern and southern hemisphere, J. Geophys. Res., 102, 25,417-25,427, 1997.
7. Chameides, W., and J.C.G. Walker, A photochemical theory of tropospheric ozone, J. Geophys. Res., 78, 8751-8760, 1973.
8. Clemitshaw, K.C., L.J. Carpenter, S.A. Penkett, and M.E. Jenkin, A calibrated peroxy radical chemical amplifier (PERCA) instrument for ground-based tropospheric measurements, J. Geophys. Res., 102, 25,405-25,416, 1997.
9. x, J. Geophys. Res., 104, 80057-8066, 1999.
10. Crutzen, P.J., Tropospheric ozone: An overview, in Tropospheric Ozone, edited by I.S.A. Isaksen, pp. 3-32, D. Reidel, Norwell, Mass., 1988.
11. Curtis, A.R., and W.P. Sweetenham, FACSIMILE/CHEKMAT Users Manual, AERE R12805, Her Majesty's Stn. Off., London, 1987.
12. De More, W.B., S.P. Sander, C.J. Howard, A.R. Ravishankara, D.M. Golden, C.E. Kolb, R.F. Hampson, M.J. Kurylo, and M.J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation number 12, JPL Publ. 97-4, 1997.
13. 1D) and primary OH production rates over the Atlantic Ocean between 50°N and 30°S, J. Atmos. Chem., 15, 283-298, 1992.
14. Jenkin, M.E., Modelling the performance of the PERCA technique as a function of altitude, AEA Technol. Rep. AEA/RAMP/20147001-/R002, AEA Technol., Culham, Oxfordshire, England, 1997.
15. Junkermann, W., U. Platt, and A. Volz-Thomas, A photoelectric detector for the measurement of photolysis frequencies of ozone and other atmospheric molecules, J. Atmos. Chem., 8, 203-227, 1989.
16. Kleinman, L.I., Y.N. Lee, S.R. Stephen, R. Springston, J.H. Lee, L. Nunnermacker, J. Weinstein-Loyd, and X. Zhou, Peroxy radical concentration and ozone formation rate at a rural site in the southeastern United States, J. Geophys. Res., 100, 7263-7273, 1995.
17. Logan, J.A., Tropospheric ozone: Seasonal behavior, trends, and anthropogenic influence, J. Geophys. Res., 90, 10,463-10,482, 1985.
18. Lugauer, M., U. Baltensperger, M. Furger, H.W. Gäggeler, D.T. Jost, M. Schwikowski, and H. Wanner, Aerosol transport to the high Alpine sites Jungfraujoch(3454 m asl) and Colle Gnifetti (4452 m asl), Tellus, Ser. B, 50, 76-92, 1998.
19. Mihele, C.M., and D.R. Hastie, The sensitivity of radical amplifier to ambient water vapor, Geophys. Res. Lett., 25, 1911-1913, 1998.
20. Monks, P.S., L.J. Carpenter, S.A. Penkett, and G.P. Ayers, Nighttime peroxy radical chemistry in the remote marine boundary layer over the Southern Ocean, Geophys. Res. Lett., 23, 535-538, 1996.
21. Monks, P.S., L.J. Carpenter, S.A. Penkett, G.P. Ayers, R.W. Gillett, I.E. Galbally, and C.P. Meyer, Fundamental ozone photochemistry in the remote marine boundary layer: The SOAPEX experiment, measurement and theory, Atmos. Environ., 32, 3647-3664, 1998a.
22. Penkett, S.A., Indications and causes of ozone increase in the troposphere, in The Changing Atmosphere, edited by F.S. Rowland and I.S.A. Isaksen., p. 91, John Wiley, New York, 1988.
23. Penkett, S.A., B.M.R. Jones, K.A. Brice, and A.E.J. Eggleton, The importance of atmospheric ozone and hydrogen peroxide in oxidising sulfur dioxide in cloud and rain water, Atmos. Environ., 22, 1699-1706, 1979.
24. Penkett, S.A., P.S. Monks, L.J. Carpenter, K.C. Clemitshaw, G.P. Ayers, R.W. Gillet, I.E. Galbally, and C.P. Meyer, Relationships between ozone photolysis rates and peroxy radical concentrations in clean marine air over the Southern Ocean, J. Geophys. Res., 102, 12,805-12,817, 1997.
25. Penkett, S.A., K.C. Clemitshaw, N.H. Savage, R.A. Burgess, L.M. Cardenas, L.J. Carpenter, G.G. McFadyen, and J.N. Cape, Studies of oxidant production at the Weybourne Atmospheric Observatory in summer and winter conditions, J. Atmos. Chem., 33, 111-128, 1999.
26. Schuepbach, E., P. Zanis, P.S. Monks, and S.A. Penkett, In-situ photochemical control and long-range transport of free tropospheric ozone at Jungfraujoch in the Swiss Alps, report, 52 pp., Fed. Off. of Environ., For. and Landscape (BUWAL), Berne, Switzerland, 1996.
27. Schuepbach, E., T.D. Davies, and A.C. Massacand, An unusual spingtime ozone episode at high elevation in the Swiss Alps: Contributions both from cross-tropopause exchange and from the boundary layer, Atmos. Environ., 33, 1735-1744, 1999a.
28. Schuepbach, E., T.D. Davies, A.C. Massacand, and H. Wernli, Mesoscale modeling of vertical atmospheric transport in the Alps associated with the advection of a tropopause fold - A winter ozone episode, Atmos. Environ., in press, 1999b.
29. Schuepbach, E., P. Zanis, S.A. Penkett, P.S. Monks, and B. Buchmann, The long-term (1986-1996) ozone record at the alpine site at Jungfraujoch (46°32'/07°59'/3,580 m asl) in Switzerland: Homogeneity analysis, trend studies and in-situ photochemistry, Invited contribution from subproject TOR-2, in Proceedings of EUROTRAC Symposium '98, edited by P.M. Borell, and P. Borell, Vol. 1, pp. 214-220, WITpress, Southampton, U.K., 1999c.
30. 2 reaction: Its misapplication in atmospheric chemistry models, J. Geophys. Res., 100, 11,695-11,698, 1995.
31. Swiss Federal Laboratories for Material Testing and Research (EMPA), Technischer Bericht zum Nationalen Beobachtungsnetz für Luftfremdstoffe (NABEL), 116 p., Dubendorf, Switzerland, 1994.
32. Swiss Meteorological Institute (SMI), Annalen der Schweizerischen Meteorologischen Anstalt, 140 pp., Zurich, Switzerland, 1996.
33. Volz-Thomas, A., et al., Peroxy radical intercomparison Exercise: A joint TOR/OCTA experiment at Schauinsland 1994, in Proceedings of EUROTRAC Symposium '96, edited by M. Borell et al, pp. 621-626, Computational Mechanics Publications, Southampton, U.K., 1997.
34. Wayne R.D., Chemistry of Atmospheres, 2nd ed., pp. 22-23, Oxford Sci., New York, 1991.