A versatile stereospecific synthesis of the 1,3-disubstituted benzo[a]quinolizidine framework via 2-aryl substituted pyridines

Tetrahedron Letters

Volumn 40, Issue 51, 1999, Pages 9147-9150

  Van der Eycken, Erik ^a   Deroover, Geert ^a   Toppet, Suzanne M ^a   Hoornaert, Georges J ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

Dehalogenation; Diels Alder reactions; Nitrogen heterocycles; Pyridines

Indexed keywords

BENZO[A]QUINOLIZIDINE DERIVATIVE; HETEROCYCLIC COMPOUND; NITROGEN DERIVATIVE; PYRIDINE DERIVATIVE; QUINOLIZIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; CYCLIZATION; DEHALOGENATION; PARTIAL DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

BETULACEAE;

EID: 0033579617     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01943-7     Document Type: Article

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11. All compounds described in the whole sequence display satisfactory analytical and spectroscopic results.
12. 2′). It can easily be deduced that the C2 substituent takes an axial position whilst the C3 and C5 substituents have an equatorial position.
13. 3).
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