Phase changes and electronic properties in toroidal mesoporous molybdenum oxides

Angewandte Chemie - International Edition

Volumn 38, Issue 10, 1999, Pages 1471-1475

  Antonelli, David M ^a   Trudeau, Michel ^b  

^a UNIVERSITY OF WINDSOR   (Canada)

^b HYDRO QUÉBEC   (Canada)

Author keywords

Mesoporosity; Molybdenum; Semiconductors; Template synthesis

Indexed keywords

METAL OXIDE; MOLYBDENUM OXIDE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTALLIZATION; DIMERIZATION; ELECTRIC ACTIVITY; ELECTRIC CONDUCTIVITY; ELECTRON TRANSPORT; OXIDATION REDUCTION REACTION; PHASE TRANSITION; POROSITY; STOICHIOMETRY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY POWDER DIFFRACTION;

EID: 0033577821     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990517)38:10<1471::AID-ANIE1471>3.0.CO;2-R     Document Type: Article

References (27)

1. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartulli, J. S. Beck, Nature 1992, 359, 710-714.
2. D. M. Antonelli, J. Y. Ying, Curr. Opin. Colloid Interface Sci. 1996, 1, 523-529.
3. D. M. Antonelli, J. Y. Ying, Angew. Chem. 1996, 108, 461-464;
4. Angew. Chem. Int. Ed. Engl. 1996, 35, 426-430.
5. D. Walsh, S. Mann, Nature 1995, 377, 320-323.
6. A. Imhof, D. J. Pine, Nature 1997, 389, 948-951.
7. S. Mann, G. A. Ozin, Nature 1996, 382, 313-318.
8. H. Yang, N. Coombs, G. A. Ozin, Nature 1997, 386, 692-695.
9. Z.-R. Tian, W. Tong, J.-Y. Wang, N.-G. Duan, V. V. Krishnan, S. L. Suib, Science 1997, 276, 926-929.
10. D. M. Antonelli, A. Nakahira, J. Y. Ying, Inorg. Chem. 1996, 35, 3126-3136.
11. D. M. Antonelli, J. Y. Ying, Chem. Mater. 1996, 8, 874-881.
12. U. Ciesla, S. Schacht, G. D. Stucky, K. Unger, F. Schuth, Angew. Chem. 1996, 108, 596-600;
13. Angew. Chem. Int. Ed. Engl. 1996, 35, 541-543.
14. J. S. Reddy, A. Sayari, Catal. Lett. 1996, 38, 219-223.
15. M. S. Wong, D. M. Antonelli, J. Y. Ying, Nanostruct. Mater. 1997, 9, 165-168.
16. D. M. Antonelli, J. Y. Ting, Angew. Chem. 1998, 107, 2202-2206;
17. Angew. Chem. Int. Ed. Engl. 1995, 34, 2014-2017.
18. P. Liu, J. Liu, A. Sayari, Chem. Commun. 1997, 577-578.
19. Q. Huo, D. I. Margolese, U. Ciesla, P. Feng, T. E. Gier, P. Sieger, R. Leon, P. M. Petroff, F. Schüth, G. Stucky, Nature 1994, 368, 317-320.
20. P. T. Tanev, M. Chibwe, T. J. Pinnavaia, Nature 1994, 368, 321-323.
21. Practical surface analysis: Vol. 1: Auger and X-ray photoelectron spectroscopy (Eds.: D. Briggs, M. P. Seah), 2nd ed., Wiley, London, 1990.
22. S. O. Grim, L. J. Matienzo, Inorg. Chem. 1975, 14, 1014-1018.
23. G. A. Ozin, S. Özkar, R. A. Prokopowicz, Acc. Chem. Res. 1992, 25, 553-560.
24. Samples were prepared by grinding in a mortar and pestel in acetone and depositing on a slide. Reflectance mode spectra were run on an Ocean Optics S-2000 UV/Vis spectrometer. The band gap was calculated from the powder UV/Vis spectra as described in A. R. West, Solid State Chemistry and its Applications, Wiley, New York, 1984, pp. 75-78.
25. G. A. Ozin, Acc. Chem. Res. 1997, 30, 17-27.
26. S. Oliver, A. Kuperman, N. Coombs, A. Lough, G. A. Ozin, Nature 1995, 378, 47-50.
27. H.-P. Lin, S. Cheng, C.-Y. Mou, Chem. Mater. 1998, 10, 581-589.