Control of one- versus two-electron reduction of ubiquinone via redox- dependent recognition [11]

Journal of the American Chemical Society

Volumn 121, Issue 1, 1999, Pages 266-267

  Greaves, Michael D ^a   Niemz, Angelika ^a   Rotello, Vincent M ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

UBIQUINONE;

ELECTRON TRANSPORT; LETTER; MOLECULAR INTERACTION; MOLECULAR RECOGNITION; OXIDATION REDUCTION REACTION; PHOTOSYNTHESIS; STRUCTURE ANALYSIS;

EID: 0033550541     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982451d     Document Type: Letter

References (43)

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41. -4 M in toluene) were recorded simultaneously in a TE 104 dual cavity; the concentration of the sample was calculated from the two double integrals.
42. rad , which effectively means that the proton is shared within the hydrogen bonding network. This would present a pathway intermediate between proton transfer occurring before as opposed to after the second one-electron reduction. We are currently exploring this intriguing mechanistic possibility using density functional methodology.
43. 16