Different ways to distort a tetracapped tetrahedron on route to forming an E4M4 cubane: The case of [E4(Pd(PPh2Me)2)4][Ph2EX2]2 (E = Sb, X = Cl; E = Bi, X = Br)

Journal of the American Chemical Society

Volumn 121, Issue 18, 1999, Pages 4409-4418

  Stark, Joseph L ^a   Harms, Brian ^a   Guzman Jimenez, Ilse ^a   Whitmire, Kenton H ^a   Gautier, Régis ^b   Halet, Jean François ^b   Saillard, Jean Yves ^b  

^a RICE UNIVERSITY   (United States)

^b UNIVERSITÉ DE RENNES 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIMONY DERIVATIVE; BISMUTH DERIVATIVE; CUBANE DERIVATIVE; DIPHENYLANTIMONY CHLORIDE; DIPHENYLBISMUTH BROMIDE; PALLADIUM COMPLEX; TETRAKIS(DIPHENYLMETHYLPHOSPHINE)PALLADIUM; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0033549120     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982902u     Document Type: Article

References (89)

1. (a) Stoll, S. L.; Bott, S. G.; Barron, A. R. J. Chem. Soc., Dalton Trans. 1997, 8, 1315 and references therein.
2. (b) Power, M. B.; Barron, A. R. J. Chem. Soc., Chem. Commun. 1991, 1315.
3. (c) Power, M. B.; Ziller, J. W.; Barron, A. R. Organometallics 1992, 11, 1055.
4. Gillan, E. G.; Bott, S. G.; Barron, A. R. Chem. Mater. 1997, 9, 806.
5. Belgardt, T.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H. G. Angew. Chem., Int. Ed. Engl. 1993, 32, 1056.
6. Merzweiler, K.; Rudolph, F.; Brands, L. Naturforsh 1992, 47B, 470.
7. Uhl, W.; Graupner, R.; Layh, M.; Schütz, U. J. Organomet. Chem. 1995, 493, C1.
8. Uhl, W.; Graupner, R.; Pohlmann, M.; Pohl, S.; Saak, W. Chem. Ber. 1996, 129, 143.
9. Power, M. B.; Barron, A. R.; Hynk, D.; Robertson, H. E.; Rankin, D. W. H. Adv. Mater Optics. Electron. 1995, 5, 177.
10. Harlan, C. J.; Gillan, E. G.; Bott, S. G.; Barron, A. R. Organometallics 1996, 15, 5479.
11. Schulz, S.; Andruh, M.; Pape, T.; Heinze, T.; Roesky, H. W.; Haming, L.; Kuhn, A.; Herbst-Inner, R. Organometallics 1994, 13, 4004.
12. Gómez-Sal, P.; Martin, A.; Mena, M.; Yélamon, C. J. Chem. Soc., Chem. Commun. 1995, 2185.
13. Simon, G. L.; Dahl, L. F. J. Am. Chem. Soc. 1973, 95, 2175.
14. Fenske, D.; Basoglu, R.; Hachgenei, J.; Rogel, F. Angew. Chem., Int. Ed. Engl. 1984, 23, 160.
15. Scherer, O. J.; Dave, T.; Braun, J.; Wolmershäuser, J. J. Organomet. Chem. 1988, 350, C20.
16. Röttinger, E.; Vahrenkamp, H. Angew. Chem., Int. Ed. Engl. 1978, 17, 273.
17. Rheingold, A. L.; Foley, M. J.; Sullivan, P. J., J. Am Chem. Soc. 1982, 104, 4727.
18. Foust, A. S.; Dahl, L. F. J. Am. Chem. Soc. 1970, 92, 7337.
19. Ciani, G.; Moret, M.; Fumagalli, A.; Martinengo, S. J. Organomet. Chem. 1989, 362, 291.
20. Röttinger, E.; Vahrenkamp, H. J. Organomet. Chem. 1981, 104, 4727.
21. Trinh, T.; Teo, B. K.; Ferguson, J. A.; Meyer, T. J.; Dahl, L. F. J. Am. Chem. Soc. 1977, 99, 408.
22. Simon, G. L.; Dahl, L. F. J. Am. Chem. Soc. 1973, 95, 2164.
23. Gall, R. S.; Chu, C. T.; Dahl, L. F. J. Am. Chem. Soc. 1974, 96, 4019.
24. Gall, R. S.; Connelly, N. G.; Dahl, L. F. J. Am. Chem. Soc. 1974, 96, 4017.
25. Wei, C. H.; Wilker, G. R.; Treichel, P. M.; Dahl, L. F. Inorg. Chem. 1966, 5, 900.
26. Curtis, M. D.; Williams, P. D. Inorg. Chem. 1983, 22, 2661.
27. Schunn, R. A.; Fritchie, C. J., Jr.; Prewitt, C. T. Inorg. Chem. 1966, 5, 892.
28. Teo, B. K. Inorg. Chem. 1984, 23, 1251.
29. Teo, B. K. Inorg. Chem. 1985, 24, 4209.
30. Teo, B. K.; Longoni, G.; Chung, F. R. K. Inorg. Chem. 1984xe2 24, 1257.
31. Harris, S. Inorg. Chem. 1987, 26, 4278.
32. Harris, S. Polyhedron 1989, 8, 2843.
33. Bahn, C. S.; Tan; A.; Harris, S. Inorg. Chem. 1998, 37, 2770.
34. See also: Sung, S.-S.; Glidewell, C.; Butler, A. R.; Hoffmann, R. Inorg. Chem. 1985, 24, 3856.
35. Zebrowski, J. P.; Hayashi, R. K.; Bjarnason, A.; Dahl, L. F. J. Am. Chem. Soc. 1992, 114, 3121.
36. Fenske, D.; Persau, C. Z. Anorg. Allg. Chem. 1991, 593, 61.
37. Fenske, D.; Fleischer, H.; Persau, C. Angew. Chem., Int. Ed. Engl. 1989, 28, 1665.
38. Fenske, D.; Ohmer, J.; Merzweiler, K. Angew. Chem., Int. Ed. Engl. 1988, 27, 1512.
39. Brennen, J. G.; Siegrist, T.; Stuczyrski, S. M.; Steigerwald, M. L. J. Am. Chem. Soc. 1989, 111, 9240.
40. Whitmire, K. H.; Eveland, J. R. J. Chem. Soc., Chem. Commun. 1994, 1335.
41. Furet, E.; Le Beuze, A.; Halet, J.-F.; Saillard, J.-Y. J. Am. Chem. Soc. 1994, 116, 274 and references therein.
42. Furet, E.; Le Beuze, A.; Halet, J.-F.; Saillard, J.-Y. J. Am. Chem. Soc. 1995, 117, 4936 and references therein.
43. Halet, J. F.; Saillard, J.-Y. Struct. Bond. 1997, 87, 81 and references therein.
44. Rösch, N.; Ackeman, L.; Pacchioni. G. Inorg. Chem. 1993, 32, 2963.
45. (a) McCandlish, L. E.; Bissell, E. C.; Coucouvanis, D.; Facker, J. P.; Knox, K. J. Am. Chem. Soc. 1968, 90, 7357.
46. (b) Hollander, F. J.; Coucouvanis, D. J. Am. Chem. Soc. 1974, 96, 5646.
47. (c) Avdeef, A.; Fackler, J. P. Inorg. Chem. 1978, 17, 2182.
48. (a) Haiduc, I.; Sowerby, D. B.; Lu, S. F. Polyhedron 1995, 14, 3389.
49. (b) Liu, C. W.; Stubbs, T.; Staples, R. J.; Fackler, J. P. J. Am. Chem. Soc. 1995, 117, 9778.
50. Albright, T. A.; Yee, K. A.; Saillard, J.-Y.; Kahlal, K.; Halet, J. F.; Leigh, J. S.; Whitmire, K. H. Inorg. Chem. 1991, 30, 1179.
51. Whitmire, K. H. Adv. Organomet. Chem. 1998, 42, 1.
52. Whitmire, K. H.; Albright, T. A.; Kang, A.-K.; Churchill, M. R. Fettinger, J. C. Inorg. Chem. 1986, 25, 2799.
53. Whitmire, K. H.; Churchill, M. R.; Fettinger, J. C. J. Am. Chem. Soc. 1985, 107, 1056.
54. Scherer, O. J.; Blath, C.; Heckmann, G.; Wolmershäuser. J. Organomet. Chem. 1991, 409, C15.
55. Ahlrichs, R.; Fenske, D.; Fromm, K. Krautscheid, H.; Treutler, O. Chem. Eur. J. 1996, 2, 238.
56. Shriver, D. F.; Drezdon, M. A. The Manipulation of Air-Sensitive Compounds; Wiley: New York, 1986.
57. (a) Gordon, A. J.; Ford, R. A. The Chemist's Companion; John Wiley and Sons: New York, 1972.
58. (b) Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
59. Nunn, M.; Sowerby, D. B.; Wesolek, D. M. J. Organomet. Chem. 1983, 251, C45.
60. Wilkinson, J. F.; Challenger, F. J. Chem. Soc. 1924, 12.
61. TEXSAN: Single-Crystal Structure Analysis Software 5.0, Molecular Structure Co., The Woodlands, TX, 1990.
62. Sheldrick, G. M. SHELXTL PLUS PC 5.0, Siemens Crystallographic Research Systems, Madison, WI, 1995.
63. Shedrick, G. M. SHELXL-93, Göttingen, Germany, 1993.
64. International Tables for Crystallography, Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C; Tables 4.2.6.8. and 6.1.1.4.
65. Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
66. Ammeter, J. H.; Bürgi, H.-B.; Thibeault, J. C.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 3686.
67. Mealli, C.; Proserpio, D. J. Chem. Educ. 1990, 67, 399.
68. (a) Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
69. (b) Baerends, E. J.; Ros, P. Int. J. Quantum. Chem. 1978, S12, 169.
70. (c) te Velde, G.; Baerends, E. J. J. Comput. Phys. 1992, 99, 84.
71. Baerends E. J.; et al. Amsterdam Density Functional (ADF) program, version 2.3, Vrije Universiteit, Amsterdam, Netherlands, 1997.
72. Vosko, S. D.; Wilk, L.; Nusair, M. Can. J. Chem. 1980, 58, 1200.
73. Boerrigter, P. M.; te Velde, G.; Baerends, E. J. Int. J. Quantum Chem. 1988, 33, 87.
74. Baerends, E. J. Ph.D. Thesis, Vrije Universiteit, Amsterdam, Netherlands, 1975.
75. Steigerwald, M. L.; Rice, C. E. J. Am. Chem. Soc. 1988, 110, 4228.
76. Barrett, C. S.; Cucka, P.; Haefner, K. Acta Crystallogr. 1963, 16, 451.
77. Cucka, P.; Barrett, C. S. Acta Crystallogr. 1962, 15, 865.
78. Pratt, J. N.; Myles, K. M.; Darby, J. B., Jr.; Mueller, M. H. J. Less Common Met. 1968, 14, 427.
79. Whitmire, K. H.; Albright, T. A.; Kang, S.-K.; Churchill, M. R.; Fettinger, J. C. Inorg. Chem. 1986, 25, 2799.
80. Cisar, A.; Corbett, J. D. Inorg. Chem. 1977, 16, 2482.
81. Zhuravlev, N. N. Soviet Phys. JETP 1957, 5, 1064.
82. (a) Clegg, W.; Errington, J.; Fisher, G. A.; Hockless, D. C. R.; Norman, N. C.; Orpen, A. G.; Stratford, S. E. J. Chem. Soc., Dalton Trans. 1992, 1967.
83. (b) Clegg, W. R.; Errington, R. J.; Fisher, G. A.; Flynn, R. J.; Norman, N. C. J. Chem. Soc., Dalton Trans. 1993, 637.
84. Sheldrick, W. S.; Martin, C. Z. Naturforsch 1992, 47b, 919.
85. Stark, J. L.; Whitmire, K. H. Acta Crystallogr. 1997, C53 (6), IUC9700007/1-2.
86. Clusters with electron-deficient early-transition-metal centers have been reported. Their bonding is analyzed in ref 30.
87. Albright, T. A.; Burdett, J. K.; Whangbo, M.-H. Orbital Interactions in Chemistry; John Wiley and Sons: New York, 1985.
88. Cotton, F. A. Chemical Applications of Group Theory, 3rd ed.; John Wiley and Sons: New York, 1990.
89. Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prenctice Hall International Editions: Engelwood Cliffs, NJ, 1990.