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0009706507
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note
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While the yield of 2a-c was modest due to the relative instability of 1a-c to the oxidation conditions, we believe that the optical purity of 2a-c corresponds to that of 1a-c because almost same optical purity was identified between 1a and 3a.
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0009706339
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note
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3N and TMSCl was examined, none of the desired product was obtained.
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27
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0009704477
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note
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8a,c for 36h at room temperature, followed by acetylation afforded rac-3a in 12% yield along with rac-4a in 13% yield, indicating low catalytic activity of titanium alkoxide for hydrophosphinylation of aldehyde.
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