Unprecedented transformation of a hydrotris(pyrazolyl)borate ligand at a metal center: Synthesis and rearrangement of the first mixed Tp/Cp lanthanide complex, Sm(Tp(Me)2)2(Cp) [4]

Journal of the American Chemical Society

Volumn 121, Issue 35, 1999, Pages 8110-8111

  Lopes, I ^a   Lin, G Y ^b   Domingos, A ^a   McDonald, R ^b   Marques, N ^a   Takats, J ^b  

^a INSTITUTO TECNOLÓGICO E NUCLEAR   (Portugal)

^b UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; LANTHANIDE; LIGAND; METAL; ORGANOMETALLIC COMPOUND; PYRAZOLE DERIVATIVE;

CHEMICAL REACTION; COMPLEX FORMATION; LETTER; SYNTHESIS;

EID: 0033536473     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja984227u     Document Type: Letter

References (46)

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40. a of pyrazole, pzH, is 14.2 (Catalan, J. et al. J. Am. Chem. Soc. 1988, 110, 4105).
41. a of pyrazole, pzH, is 14.2 (Catalan, J. et al. J. Am. Chem. Soc. 1988, 110, 4105).
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43. c-e ligand systems. (a) Herberich, G. E.; Fischer, A. Organometallics 1996, 15, 58. (b) Larkin, S. A.; Golden, J. T.; Shapiro, P. J.; Yap, G. P. A.; Foo, D. M. J.; Rheingold; A. L. Organometallics 1996, 15, 2393. (c) Shafiq, F. A.; Abboud, K. A.; Richardson, D. E.; Boncella, J. M. Organometallics 1998, 17, 982. (d) Lancaster, S. J.; Thornton-Pett, M.; Dawson, D. M.; Bochmann, M. Organometallics 1998, 17, 3829.
44. c-e ligand systems. (a) Herberich, G. E.; Fischer, A. Organometallics 1996, 15, 58. (b) Larkin, S. A.; Golden, J. T.; Shapiro, P. J.; Yap, G. P. A.; Foo, D. M. J.; Rheingold; A. L. Organometallics 1996, 15, 2393. (c) Shafiq, F. A.; Abboud, K. A.; Richardson, D. E.; Boncella, J. M. Organometallics 1998, 17, 982. (d) Lancaster, S. J.; Thornton-Pett, M.; Dawson, D. M.; Bochmann, M. Organometallics 1998, 17, 3829.
45. c-e ligand systems. (a) Herberich, G. E.; Fischer, A. Organometallics 1996, 15, 58. (b) Larkin, S. A.; Golden, J. T.; Shapiro, P. J.; Yap, G. P. A.; Foo, D. M. J.; Rheingold; A. L. Organometallics 1996, 15, 2393. (c) Shafiq, F. A.; Abboud, K. A.; Richardson, D. E.; Boncella, J. M. Organometallics 1998, 17, 982. (d) Lancaster, S. J.; Thornton-Pett, M.; Dawson, D. M.; Bochmann, M. Organometallics 1998, 17, 3829.
46. 2pz) already at 100°C; Lin, G. Y.; Takats, J. Manuscript in preparation.