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0344580680
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note
-
Phosphonate 31 was prepared by heating trimethyl phosphite and 3-(trimethylsilyl)propynyl bromide followed by deprotonation with BuLi and subsequent treatment with MeI. Phosphonate 32 was prepared in analogous fashion starting with triisopropyl phosphite.
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45
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54
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0345011660
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note
-
13C NMR spectrum of synthetic 1 did not match that reported in the original isolation paper (ref 4a). However, this discrepancy proved to be the result of a typographical error in the isolation paper as confirmed by Dr. R. Jansen by personal communication.
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