A comparison of NH-π versus lone pair hydrogen bonding effects on carbon acid pK(a) shifts [10]

Journal of the American Chemical Society

Volumn 121, Issue 26, 1999, Pages 6324-6325

  Snowden, Timothy S ^a   Bisson, Adrian P ^a   Anslyn, Eric V ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

4 CHLOROBENZOATE DEHALOGENASE;

CRYSTAL STRUCTURE; ENZYME ACTIVE SITE; ENZYME CONFORMATION; ENZYME STABILITY; HYDROGEN BOND; LETTER; MOLECULAR STABILITY;

EID: 0033532872     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991039a     Document Type: Letter

References (25)

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17. 1H NMR complexation studies have values below 9.3 ppm and are not indicative of low-barrier hydrogen bond formation.
18. 2 is expected to have a broader pH scale than acetonitrile, based upon its lower dielectric constant.
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24. a determinations, were performed on a mixture of enol and keto forms.
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