The first examples of selective carbonylation of n-butane and n-pentane

Tetrahedron Letters

Volumn 40, Issue 32, 1999, Pages 5897-5900

  Akhrem, Irena ^a   Orlinkov, Alexander ^a   Afanas'eva, Lyudmila ^a   Petrovskii, Pavel ^a   Vitt, Sergei ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

BUTANE; CARBON MONOXIDE; INORGANIC ACID; PENTANE;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; REACTION ANALYSIS; STEREOCHEMISTRY; STOICHIOMETRY;

EID: 0033529881     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01125-9     Document Type: Article

References (16)

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8. 3) was carefully added, reaction mixture was left to warm up to room temperature and then stirred during additional 30 min. After water workup and extraction with ether, reaction products were analyzed by GC and GC-MS with undecanone-2 as internal standard.
9. 1H NMR: 0.89 (3H, t, J = 7.4), 1.09 (3H, d, J = 7.0), 1.21 (6H, d, J = 6.3), 1.43 (1H, m), 1.63 (1H, m), 2.29 (1H, m), 4.96 (1H, sept, J = 6.3); MS: 144 (1), 129 (5), 116 (22), 103 (43), 102 (14), 87 (19), 85 (76), 74 (45), 59 (30), 57 (100), 56 (48); 3, MS: 158 (4), 143 (13), 130(47), 117 (56), 99 (82), 88 (71), 87 (39), 73 (20), 72 (70), 71, (100), 59 (53).
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