On the 'rebound' mechanism of alkane hydroxylation by cytochrome P450: Electronic structure of the intermediate and the electron transfer character in the rebound step

Angewandte Chemie - International Edition

Volumn 38, Issue 23, 1999, Pages 3510-3512

  Filatov, Michael ^a   Harris, Nathan ^a   Shaik, Sason ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Alkane hydroxylations; C H activation; CytoChrome P450; Density functional calculations; Enzyme catalysis

Indexed keywords

CYTOCHROME P450;

ARTICLE; CALCULATION; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; ENZYME MECHANISM; HYDROXYLATION; REACTION ANALYSIS;

EID: 0033521186     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19991203)38:23<3510::aid-anie3510>3.0.co;2-%23     Document Type: Article

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