Controlled arrangement of supramolecular metal coordination arrays on surfaces

Angewandte Chemie - International Edition

Volumn 38, Issue 17, 1999, Pages 2547-2550

  Semenov, Alexander ^a   Spatz, Joachim P ^a   Möller, Martin ^a   Lehn, Jean Marie ^b   Sell, Bernd ^c   Schubert, Dieter ^c   Weidl, Christian H ^d   Schubert, Ulrich S ^d  

^a UNIVERSITY OF ULM   (Germany)

^b UNIVERSITÉ LOUIS PASTEUR   (France)

^c GOETHE UNIVERSITY   (Germany)

^d TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

Metallic grids; Monolayers; Ordered architectures; Scanning tunneling microscopy; Supramolecular chemistry

Indexed keywords

COORDINATION COMPOUND; GRAPHITE; LIGAND; METAL;

ADSORPTION; ARTICLE; LIGAND BINDING; MOLECULAR INTERACTION; NANOPARTICLE; REACTION ANALYSIS; SURFACE PROPERTY;

EID: 0033520280     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990903)38:17<2547::AID-ANIE2547>3.0.CO;2-M     Document Type: Article

References (29)

1. J.-M. Lehn, Supramolecular Chemistry - Concepts and Perspectives, VCH, Weinheim, 1995; J.-M. Lehn, Macromol. Chem. Macromol. Symp. 1993, 69, 1-17.
2. J.-M. Lehn, Supramolecular Chemistry - Concepts and Perspectives, VCH, Weinheim, 1995; J.-M. Lehn, Macromol. Chem. Macromol. Symp. 1993, 69, 1-17.
3. D. S. Lawrence, T. Jiang, M. Levett. Chem. Rev. 1995, 2229-2260; M. Kotera, J.-M. Lehn, J.-P. Vigneron, J. Chem. Soc. Chem. Commun. 1994, 197-199.
4. D. S. Lawrence, T. Jiang, M. Levett. Chem. Rev. 1995, 2229-2260; M. Kotera, J.-M. Lehn, J.-P. Vigneron, J. Chem. Soc. Chem. Commun. 1994, 197-199.
5. a) J.-M. Lehn, A. Rigault, J. Siegel, J. Harrowfield, B. Chevrier, D. Moras. Proc. Natl. Acad. Sci. USA 1987, 84, 2565-2569;
6. b) P. N. W. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92-95; Angew. Chem. Int. Ed. Engl. 1993, 32, 69-72;
7. b) P. N. W. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92-95; Angew. Chem. Int. Ed. Engl. 1993, 32, 69-72;
8. c) E. C. Constable, Prog. Inorg. Chem. 1994, 42, 67-138;
9. d) C. Piguet, G. Bernardinelli, G. Hopfgarten, Chem. Rev. 1997, 97, 2005-2062.
10. G. S. Hanan, U. S. Schubert, D. Volkmer, E. Riviere, J.-M. Lehn, N. Kyritsakas, J. Fischer, Can. J. Chem. 1997, 75, 169-182.
11. G. S. Hanan, D. Volkmer, U S. Schubert, J.-M. Lehn, G. Baum, D. Fenske, Angew. Chem. 1997, 109, 1929-1931; Angew. Chem. Int. Ed. Engl. 1997, 36, 1842-1844. G. S. Hanan, U S. Schubert, D. Volkmer, J.-M. Lehn, J. Hassmann, C. Y. Hahn, O. Waldmann, P. Müller, G. Baum, D. Fenske in Molecular Recognition and Inclusion (Ed.: A. Colman), Kluwer, Dordrecht, 1998, pp. 349-352.
12. G. S. Hanan, D. Volkmer, U S. Schubert, J.-M. Lehn, G. Baum, D. Fenske, Angew. Chem. 1997, 109, 1929-1931; Angew. Chem. Int. Ed. Engl. 1997, 36, 1842-1844. G. S. Hanan, U S. Schubert, D. Volkmer, J.-M. Lehn, J. Hassmann, C. Y. Hahn, O. Waldmann, P. Müller, G. Baum, D. Fenske in Molecular Recognition and Inclusion (Ed.: A. Colman), Kluwer, Dordrecht, 1998, pp. 349-352.
13. G. S. Hanan, D. Volkmer, U S. Schubert, J.-M. Lehn, G. Baum, D. Fenske, Angew. Chem. 1997, 109, 1929-1931; Angew. Chem. Int. Ed. Engl. 1997, 36, 1842-1844. G. S. Hanan, U S. Schubert, D. Volkmer, J.-M. Lehn, J. Hassmann, C. Y. Hahn, O. Waldmann, P. Müller, G. Baum, D. Fenske in Molecular Recognition and Inclusion (Ed.: A. Colman), Kluwer, Dordrecht, 1998, pp. 349-352.
14. O. Waldmann, J. Hassmann, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. Lett. 1997, 78, 3390-3393; J. Hassmann, C. Y. Hahn, O. Waldmann, E. Volz, H.-J. Schleemilch, N. Hallschmid, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, H. Mauser, A. Hirsch, Mat. Res. Soc. Symp. Proc. 1998, 448, 447-452; O. Waldmann, J. Hassmann, R. Koch, P. Müller, G.S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Mat. Res. Soc. Symp. Proc. 1998, 448, 841-846; O. Waldmann, J. Hassmann, P. Müller, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. B 1998, 58, 3277- 3285.
15. O. Waldmann, J. Hassmann, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. Lett. 1997, 78, 3390-3393; J. Hassmann, C. Y. Hahn, O. Waldmann, E. Volz, H.-J. Schleemilch, N. Hallschmid, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, H. Mauser, A. Hirsch, Mat. Res. Soc. Symp. Proc. 1998, 448, 447-452; O. Waldmann, J. Hassmann, R. Koch, P. Müller, G.S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Mat. Res. Soc. Symp. Proc. 1998, 448, 841-846; O. Waldmann, J. Hassmann, P. Müller, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. B 1998, 58, 3277- 3285.
16. O. Waldmann, J. Hassmann, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. Lett. 1997, 78, 3390-3393; J. Hassmann, C. Y. Hahn, O. Waldmann, E. Volz, H.-J. Schleemilch, N. Hallschmid, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, H. Mauser, A. Hirsch, Mat. Res. Soc. Symp. Proc. 1998, 448, 447-452; O. Waldmann, J. Hassmann, R. Koch, P. Müller, G.S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Mat. Res. Soc. Symp. Proc. 1998, 448, 841-846; O. Waldmann, J. Hassmann, P. Müller, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. B 1998, 58, 3277- 3285.
17. O. Waldmann, J. Hassmann, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. Lett. 1997, 78, 3390-3393; J. Hassmann, C. Y. Hahn, O. Waldmann, E. Volz, H.-J. Schleemilch, N. Hallschmid, P. Müller, G. S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, H. Mauser, A. Hirsch, Mat. Res. Soc. Symp. Proc. 1998, 448, 447-452; O. Waldmann, J. Hassmann, R. Koch, P. Müller, G.S. Hanan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Mat. Res. Soc. Symp. Proc. 1998, 448, 841-846; O. Waldmann, J. Hassmann, P. Müller, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. B 1998, 58, 3277-3285.
18. U. S. Schubert, C. H. Weidl, J.-M. Lehn, Design. Monom. Polym. 1999, 2, 1-7.
19. R. C. Ashoori, Nature 1996, 379, 413-419.
20. J. R. Friedman, M. P. Sarachik, J. Tejada, R. Ziolo, Phys. Rev. Lett. 1996, 76, 3830-3833.
21. U. S. Schubert, J.-M. Lehn, J. Hassmann, C. Y. Hahn, N. Hallschmidt, P. Müller, ACS Symp. Ser. 1998, 704, 248-260.
22. I. Weissbuch, P. N. W. Baxter, S. Cohen, H. Cohen, K. Kjaer, P. B. Howes, J. Als-Nielsen, G. S. Hanan, U. S. Schubert, J.-M. Lehn, L. Leiserowitz, M. Lahav, J. Am. Chem. Soc. 1998, 120, 4850-4860.
23. A. Semenov, J. P. Spatz, J.-M. Lehn, C. H. Weidl, U. S. Schubert, M. Möller, Appl. Surface Sci., in press.
24. D. Schubert, J. A. van den Broek, B. Sell, H. Durchschlag, W. Mächtle, U. S. Schubert, J.-M. Lehn, Prog. Colloid Polym. Sci. 1997, 107, 166-177 ; D. Schubert, C. Tziatzios, P. Schuck, U. S. Schubert, Chem. Eur. J. 1999, 5, 1377-1383.
25. D. Schubert, J. A. van den Broek, B. Sell, H. Durchschlag, W. Mächtle, U. S. Schubert, J.-M. Lehn, Prog. Colloid Polym. Sci. 1997, 107, 166- 177 ; D. Schubert, C. Tziatzios, P. Schuck, U. S. Schubert, Chem. Eur. J. 1999, 5, 1377-1383.
26. The diagonal dark and light variations forming a superstructure parallel to the molecular rows in Figures 2a and 2c are assigned to a variation of charge density, which is rather common in the STM analysis of layered materials, see for example: R. Wiesendanger, D. Anselmetti in Scanning Tunneling Microscopy 1 (Eds.: H.-J. Güntherodt, R. Wiesendanger), Springer, Berlin, 1994, pp. 131-179.
27. The local electron density distribution was calculated by using the force-field method MM+ (Hyperchem) for the grid geometry surrounded by eight anions (optimization for isolated grids, in contrast to the crystal situation). The graphite support presented by four monolayers was included in the model for geometry simulation. The quantum mechanical method ZINDO/1 was used for electron-density calculations.
28. P. Schuck, Prog. Colloid Poly. Sci. 1994, 94, 1-13; P. Schuck, B. Legrum, H. Passow, D. Schubert, Eur. J. Biochem. 1995, 230, 806-812.
29. P. Schuck, Prog. Colloid Poly. Sci. 1994, 94, 1-13; P. Schuck, B. Legrum, H. Passow, D. Schubert, Eur. J. Biochem. 1995, 230, 806-812.