A zwitterionic λ5Si-silicate with an almost ideal square-pyramidal Si coordination polyhedron: Synthesis and crystal structure analysis

Monatshefte fur Chemie

Volumn 130, Issue 1, 1999, Pages 99-107

  Tacke, Reinhold ^a   Heermann, Joachim ^a   Pülm, Melanie ^a   Gottfried, Elmar ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Crystal structure analysis; Pentacoordinate silicon; Solid state 29 Si NMR; Solution state 29Si NMR; Zwitterionic 5Si silicate

Indexed keywords

EID: 0033479982     PISSN: 00269247     EISSN: None     Source Type: Journal    
DOI: 10.1007/PL00010179     Document Type: Article

References (23)

1. a) Strohmann C, Tacke R, Mattern G, Kuhs WF (1991) J Organomet Chem 403: 63;
2. b) Tacke R, Sperlich J, Strohmann C, Mattern G (1991) Chem Ber 124: 1491;
3. c) Tacke R, Sperlich J, Strohmann C, Frank B, Mattern G (1992) Z Kristallogr 199: 91;
4. d) Tacke R, Wiesenberger F, Lopez-Mras A, Sperlich J, Mattern G (1992) Z Naturforsch, Part B 47: 1370;
5. e) Tacke R, Lopez-Mras A, Sperlich J, Strohmann C, Kuhs WF, Mattern G, Sebald A (1993) Chem Ber 126: 851;
6. f) Tacke R, Lopez-Mras A, Sheldrick WS, Sebald A (1993) Z Anorg Allg Chem 619: 347;
7. g) Tacke R, Becht J, Lopez-Mras A, Sperlich J (1993) J Organomet Chem 446: 1;
8. h) Sperlich J, Becht J, Mühleisen M, Wagner SA, Mattern G, Tacke R (1993) Z Naturforsch, Part B 48: 1693;
9. i) Tacke R, Mütileisen M, Lopez-Mras A, Sheldrick WS (1995) Z Anorg Allg Chem 621: 779
10. Dannappel O, Tacke R (1996) Intramolecular Ligand Exchange of Zwitterionic Spirocyclic Bis(1,2-benzenediolato(2-))organosilicates: Ab initio Studies of the Bis[1,2-benzenediolato(2-)]hydridosilicate(1-) Ion. In: Auner N, Weis J (eds) Organosilicon Chemistry II. Verlag Chemie, Weinheim, p 453
11. Tacke R, Pfrommer B, Lunkenheimer K, Hirte R (1998) Organometallics 17: 3670 and references cited therein
12. a) Tandura SN, Voronkov MG, Alekseev NV (1986) Top Curr Chem 131: 99;
13. b) Sheldrick WS (1989) Structural Chemistry of Organic Silicon Compounds. In: Patai S, Rappoport Z (eds) The Chemistry of Organic Silicon Compounds, Part I. Wiley, Chichester, UK, p 227;
14. c) Holmes RR (1990) Chem Rev 90: 17;
15. d) Chuit C, Corriu RJP, Reye C, Young JC (1993) Chem Rev 93: 1371;
16. e) Wong CY, Woollins JD (1994) Coord Chem Rev 130: 175;
17. f) Lukevics E, Pudova OA (1996) Chem Heterocycl Compd 353: 1605;
18. g) Holmes RR (1996) Chem Rev 96: 927
19. Becht J (1994) Thesis, University of Karlsruhe, Germany
20. Kottke T, Lagow RJ, Stalke D (1996) J Appl Crystallogr 29: 465
21. Sheldrick GM SHELXS-96 (1996) University of Göttingen, Germany; Sheldrick GM (1990) Acta Crystallogr A 46: 467
22. Sheldrick GM SHELXS-96 (1996) University of Göttingen, Germany; Sheldrick GM (1990) Acta Crystallogr A 46: 467
23. Sheldrick GM SHELXL-96 (1996) University of Göttingen, Germany