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NALORAC Corporation, 841A Arnold Drive, Martinez, CA, 94553, email: sales@nalorac.com.
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85033944352
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note
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4 (-63.5 ppm) assumed temperature independent.
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32
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85033965385
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note
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The NMR resonances detected in this period, when the temperature in the ampoule is changing rapidly, are broad and ill-shaped because they move during signal acquisition as a result of the temperature dependence of their chemical shifts. Furthermore, they cannot be compared with those obtained at thermal equilibrium since NMR intensities vary inversely with temperature (Curie law). With reagents that are liquid at room temperature, the situation is even worse since in the first few minutes the internal vapor pressure, and therefore the signal strength, changes rapidly as the temperature is rising.
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0029799560
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