Two-dimensional honeycomb network formed by porphyrinatomanganese(III) and μ4-σ-dimerized 7,7,8,8-tetracyano-p-quinodimethane dianion

Chemistry Letters

Volumn , Issue 5, 1999, Pages 413-414

  Mikami, Shinji ^a   Sugiura, Ken Ichi ^a   Miller, Joel S ^b   Sakata, Yoshiteru ^a  

^a OSAKA UNIVERSITY   (Japan)

^b UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033450482     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.413     Document Type: Article

References (29)

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15. 16: C, 75.93; H, 5.38; Cl, 5.57; N, 8.80 %. This composition was used for the diamagnetic correction.
16. H. Zhao, R. A. Heintz, K. R. Dunbar, and R. D. Rogers, J. Am. Chem. Soc., 118, 12844 (1996).
17. max = 55.0°, R (Rw) = 0.074 (0.113), Goodness-of-Fit = 1.96, reflection-parameter ratio = 11.43 based on 9062 unique reflections with I > 3σ(I). Data were collected on a Rigaku R-AXIS IV imaging plate area detector system with a graphite monochromated Mo-Kα radiation (60 KV X 300 mA), and the structure was solved by a teXsan crystallographic software package from Rigaku. A total of 40 oscillation images with 4.50° oscillation angles were collected, each being exposed for 45.0 min. 12872 reflections were collected. Importanet structural parameters for the dianion are the followings; Mn(1)-N(7): 2.264(5), Mn(2)-N(8): 2.277(4), N(5)-C(67): 1.143(7), N(6)-C(68): 1.152(9), N(7)-C(58): 1.158(8), N(8)-C(59): 1.156(6), C(57)-C(58): 1.405(8), C(57)-C(59): 1.391(6), C(57)-C(60): 1.449(5), C(60)-C(61): 1.406(5), C(60)-C(62): 1.402(7), C(61)-C(63): 1.377(6), C(62)-C(64): 1.376(5), C(63)-C(65): 1.397(8), C(64)-C(65): 1.379(5), C(65)-C(66): 1.529(5), C(66) C(66*): 1.61(1), C(66)-C(67): 1.471(7), C(66)-C(68): 1.477(9) Å, Mn(1)-N(7)-C(58): 136.8(5)°, Mn(2)-N(8)-C(59): 147.1(4)°, C(65)-C(66)-C(66): 111.8(5)°, C(65)-C(66)-C(67): 111.0(4)°, C(65)-C(66)-C(68): 111.0(3)°, C(66)-C(66)-C(67): 107.9(4)°, C(66)-C(66)-C(68): 107.2(5)°, C(67)-C(66)-C(68): 107.7(5)°.
18. The corresponding values for the reported same dianion are the followings. a) 1.65(2) Å: V. Dong, H. Endres, H. J. Keller, W. Moroni, and D. Nöthe, Acta Crystallogr., Sect B, 33, 2428 (1977).
19. b) 1.631(4) Å: B. Morosin, H. J. Plastas, L. B. Coleman, and J. M. Stewart, Acta Crystallogr., Sect B, 34, 540 (1978).
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21. d) 1.659(10) and 1.635(10) Å: in Ref. 10.
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25. *_ was reported to show ferrimagnetic 1-D chain interacts antiferromagnetically. a) E. Dormann, Synth. Met., 71, 1781 (1995).
26. b) H. Winter, M. Kelemen, E. Dormann, R. Gompper, R. Janner, S. Kothrade, and B. Wagner, Mol. Cryst. Liq. Cryst., 273, 111 (1995).
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29. d) J. S. Miller, C. Vazquez, and R. S. McLean, unpublished results.