Gallium speciation in aqueous solution. Experimental study and modelling: Part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250°C and hydrolysis constants of gallium (III) to 300°C

Geochimica et Cosmochimica Acta

Volumn 61, Issue 7, 1997, Pages 1345-1357

  Bénézeth, Pascale ^a,c   Diakonov, Igor I ^a   Pokrovski, Gleb S ^a   Dandurand, Jean Louis ^a   Schott, Jacques ^a   Khodakovsky, Igor L ^b  

^a CNRS   (France)

^b VERNADSKY INSTITUTE OF GEOCHEMISTRY AND ANALYTICAL CHEMISTRY   (Russian Federation)

^c OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC SOLUTION; GALLIUM HYDROXIDE OXIDE; HYDROLYSIS; SOLUBILITY;

EID: 0030860162     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(97)00012-4     Document Type: Article

References (55)

1. 71Gallium nuclear magnetic resonance investigation of aqueous gallium(III) and its hydrolysis. Magn. Reson. Chem. 27, 377-379.
2. Baes C. F., Jr, and Mesmer R. E. (1976) The Hydrolysis of Cations. Wiley.
3. Bertine K. K. and Goldberg E. A. (1971) Fossil fuel combustion and the major sedimentary cycle. Science 173, 233-235.
4. Biryuk E. A. and Nazarenko V. A. (1973) Determination of hydrolysis constants of monomeric gallium ions in solutions with ionic strength 0.1-1.0. Russ. J. Inorg. Chem. 18, 1576-1578.
5. Brown P. L. (1989) The hydrolysis of metals ions. Part 11. The ionic strength dependence of gallium(III). J. Chem. Soc. Dalton. Trans., 399-402.
6. Burton J. D. and Culkin F. (1972) Gallium. In Handbook of Geochemistry (ed. K. H. Wederpohl), parts 31B-310. Springer-Verlag.
7. Campisi A. and Tregloan P. A. (1985) Kinetics and equilibria of Ga(III)-Thiocyanate complex formation. Mechanism of ligand substitution reactions of Ga(III) in aqueous solution. Inorg. Chim. Acta 100, 251-259.
8. Castet S., Dandurand J. L., Schott J., and Gout R. (1993) Boehmite solubility and aqueous aluminum speciation in hydrothermal solutions (90-350°C). Experimental study and modeling. Geochim. Cosmochim. Acta 57, 4869-4884.
9. Devidal J. L. (1994) Solubilité et cinétique de dissolution/précipitation de la kaolinite en milieu hydrothermal. Approche expérimentale et modélisation. Thèse de l'Univ. Paul-Sabatier, Toulouse.
10. 4 to 300°C. Geochim. Cosmochim. Acta. (this issue).
11. Feitknecht W. and Schindler P. (1963) Solubility constants of metal oxides, metal hydroxides, and metal hydroxide salts in aqueous solution. Pure Appl. Chem. 6, 130-199.
12. Fetter N. R. (1957) The equilibria of crystalline gallium oxide monohydrate in dilute solutions of perchloric acid and sodium hydroxide at 25°C. Ph.D. Thesis, Univ. Oregon.
13. Fricke R. and Blencke (1925) Beiträge zur Chemie des Galliums. Z. Anorg. Allgem. Chem. 143, 183-200.
14. Fricke R. and Meyring K. (1928) Beiträge zur Chemie des Galliums. II. Z. Anorg. Allgem. Chem. 176, 325-348.
15. Gamsjäger H. and Schindler P. (1967) Die Löslichkeit von α-GaO(OH) bei 60°C in perchlorsauren Lösungen konstanter Ionenstärke. Helv. Chim. Acta 50, 2053-2057.
16. 4 bei 60°C. Helv. Chim. Acta 52, 2315-2327.
17. Gimblett F. G. R. (1971) Particle growth and precipitation in hydrolyzed gallium (III) perchlorate solutions. J. Inorg. Nucl. Chem. 33, 2887-2903.
18. Goldschmidt V. M. (1954) Geochemistry. Oxford Univ. Press.
19. Cl- = 3M). J. Chim. Phys. Physiochim. Biol. 64, 1338.
20. Helgeson H. C. and Kirkham D. H. (1974) Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures: II. Debye-Hückel parameters for activity coefficients and relative partial molal properties. Amer. J. Sci. 274, 1199-1261.
21. Hieronymus B., Boulegue J., and Kotschoubey B. (1990) Gallium behavior in some intertropical environment alterations. Geochem. Earth's Surf. Min. Form. 2nd Intl. Symp., Aix en Provence, France, Chem. Geol. 84, 78-82.
22. Horn M. K. and Adams J. A. S. (1966) Computer-derived geochemical balances and element abundances. Geochim. Cosmochim. Acta 30, 279-297.
23. Hovey J. K. (1988) Thermodynamics of aqueous solutions. Ph.D. Thesis, Univ. Alberta.
24. Ivanov-Emin B. N., Nisel'son L. A., and Larionova L. E. (1962) Alkali metal gallate solutions. Russ. J. Inorg. Chem. 7, 266-268.
25. Johnson J. W., Oelkers H. E., and Helgeson H. C. (1992) SUPCRT92. A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C. Comput. Geosci. 18, 899-947.
26. Kopeykin V. A. (1984) Geochemical features of the behavior of gallium in laterization. Geochem. Intl. 14, 16-20.
27. Kudryashov B., Davidov Yu., and Mironov B. (1986) 2ème conférence de la chimie analytique de solutions d'électrolytes, Moscou, 2-4 décembre, p20.
28. 3+. Masson.
29. Laubengayer A. W. and Engle H. R. (1939) The sesquioxide and hydroxides of gallium. J. Amer. Chem. Soc. 61, 1210-1214.
30. Maring H. R. and Duce R. A. (1987) The impact of atmospheric aerosols on trace metal chemistry in open ocean surface seawater. 1. Aluminum. Earth Planet. Sci. Lett. 84, 381-392.
31. Martin F. (1994) Etude cristallographique et cristallochimique de l'incorporation du germanium et du gallium dans les phyllosilicates. Approche par synthèse minérale. Thèse de l'Univ. Aix, Marseille.
32. Moeller T. and King G. L. (1950) Some physicochemical studies on Gallium(III) salt solutions. J. Phys. Colloid Chem. 54, 999-1011.
33. Nazarenko V. A., Antonovich V. P., and Nevskaya E. M. (1968) Spectrophotometric determination of the hydrolysis constants of gallium ions. Russ. J. Inorg. Chem. 13, 825-828.
34. Oka Y. (1938) The fundamental reactions in analytical chemistry. IX. Summary. J. Chem. Soc. Japan 59, 971.
35. Orians K. J. and Bruland K. W. (1988a) Dissolved gallium in the open ocean. Nature 21, 717-719.
36. Orians K. J. and Bruland K. W. (1988b) The marine geochemistry of dissolved gallium. A comparison with dissolved aluminum. Geochim. Cosmochim. Acta 52, 2955-2962.
37. Palmer D. A. and Wesolowski D. J. (1992) Aluminum speciation and equilibria in aqueous solution: II. The solubility of gibbsite in acidic sodium chloride solutions from 30 to 70°C. Geochim. Cosmochim. Acta 56, 1093-1111.
38. Palmer D. A. and Wesolowski (1993) Aluminum speciation and equilibria in aqueous solution: III. Potentiometric determination of the first hydrolysis constant of aluminum (III) in sodium chloride solutions to 125°C. Geochim. Cosmochim. Acta 57, 2929-2938.
39. Pokrovski G. et al. (1996) Thermodynamic properties of gallium hydroxide (αGaOOH) at temperatures to 700K. Submitted to Eur. J. Miner.
40. Ruaya J. R. and Seward T. M. (1987) The ion-pair constant and other thermodynamic properties of HCl up to 350°C. Geochim. Cosmochim. Acta 51, 121-130.
41. Saltman W. M. and Nachtrieb N. H. (1953) The electrochemistry of gallium. J. Electrochem. Soc. 100, 126-130.
42. Shan X. Q., Yuan Z. N., and Ni Z. M. (1985) Determination of gallium in sediment, coal, coal fly ash, and botanical samples by Graphite Furnace Atomic Absorption Spectrometry using nickel matrix modification. Anal. Chem. 57, 857-861.
43. Shannon R. D. and Prewitt C. D. (1969) Effective ionic radii in oxides and fluorides. Acta Cryst. B25, 925-946.
44. Shiller A. M. (1988) Enrichment of dissolved gallium relative to aluminum in natural waters. Geochim. Cosmochim. Acta 52, 1879-1882.
45. Shiller A. M. and Frilot D. M. (1996) The geochemistry of gallium relative to aluminum in California streams. Geochim. Cosmochim. Acta 60, 1323-1328.
46. Shock E. L. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high temperatures and pressures: Correlation algorithms for ionic species and equation of state predictions to 5 kbar and 1000°C. Geochim. Cosmochim. Acta 52, 2009-2036.
47. Shock E. L., Oelkers E. H., Johnson J. W., Sverjensky D. A., and Helgeson H. C. (1992) Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures: Effective electrostatic radii, dissociation constants and standard partial molal properties to 1000°C and 5 kbar. J. Chem. Soc. Faraday Trans. 88, 803-826.
48. Shvarov Y. V. (1997) "UT-HEL": A BASIC computer code for calculating the revised HKF equations of state parameters for aqueous speceters for aqueous species. Version 2-0. Submitted to Software Notice, Amer. Miner.
49. Stoch L. (1984) Significance of structural factors in dehydroxylation of kaolinite polytypes. J. Therm. Anal. 29, 161-166.
50. Stumm W. and Morgan J. J. (1981) Aquatic Surface Chemistry. 2nd edition. Wiley.
51. Tanger J. C. and Helgeson H. C. (1988) Revised equation of state for the standard partial molal properties of ions and electrolytes. Amer. J. Sci. 288, 19-98.
52. 3 solutions with evaluation of regression methods. Ph.D. Thesis, Univ. Utrecht.
53. Viers J., Dupre B., Polve M., Schott J., Dandurand J. L., and Braun J. J. (1996) Geochemistry of major, trace elements and dissolved organic carbon in waters (ground and river water) draining lateritic soils in a tropical area: Nsimi-Zoetele (Cameroon, Central Africa). Submitted to Chem. Geol.
54. 2 organic substances in SI units. J. Phys. Chem. Ref. Data 11 (suppl. 2), pp. 131-132.
55. Wesolowski D. J. and Palmer D. A. (1994) Aluminum speciation and equilibria in aqueous solution: V. Gibbsite solubility at 50°C and pH 3 to 9 in 0.1 molal NaCl solutions (a general model for aluminum speciation; analytical methods). Geochim. Cosmochim. Acta 58