The decomposition of methyl hemiacetals of benzaldehyde in aqueous solution: A study of the effect of aromatic substitution

Canadian Journal of Chemistry

Volumn 77, Issue 5-6, 1999, Pages 978-989

  Engell, Karen M ^a   McClelland, Robert A ^b   Sørensen, Poul E ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^b UNIVERSITY OF TORONTO   (Canada)

Author keywords

Acid base catalysed breakdown; Hammett plots; Methyl hemiacetals of benzaldehydes; More O'Ferrall Jencks diagrams

Indexed keywords

CARBONYL COMPOUNDS; CATALYSIS; CATALYSTS; SOLUTIONS;

ACID BASE; ACID–BASE CATALYZED BREAKDOWN; BASE CATALYSIS; BASE CATALYZED; COMPUTER GRAPHICS [1.3.7]: THREE-DIMENSIONAL GRAPHICS AND REALISM - VIRTUAL REALITIES; ELECTROPHILES; HAMMETT PLOTS; HEMIACETALS; METHYL HEMIACETAL OF BENZALDEHYDE; MORE O’FERRALL – JENCKS DIAGRAM.;

NUCLEOPHILES;

ACETAL; ACID; AROMATIC COMPOUND; BASE; BENZALDEHYDE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; DECOMPOSITION; PROTON TRANSPORT; REACTION ANALYSIS;

EID: 0033306502     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v99-102     Document Type: Article

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