Synthesis and reactions of a 1-germaallene kinetically stabilized by 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl group

Phosphorus, Sulfur and Silicon and Related Elements

Volumn 150-151, Issue , 1999, Pages 137-143

  Tokitoh, Norihiro ^a,b   Kishikawa, Kuniyuki ^a   Okazaki, Renji ^a,c  

^a UNIVERSITY OF TOKYO   (Japan)

^b KYUSHU UNIVERSITY   (Japan)

^c JAPAN WOMEN'S UNIVERSITY   (Japan)

Author keywords

(l chlorovinyl)chlorogermane; Alkylidenetelluragermirane; l germaallene; Reductive dechlorination; Steric protection

Indexed keywords

EID: 0033234448     PISSN: 10426507     EISSN: None     Source Type: Journal    
DOI: 10.1080/10426509908546378     Document Type: Article

References (17)

1. F. G. A. Stone and R. West, Eds., Adv. Organomet. Chem., 39, 71, 232, and 275 (1996).
2. a) N. Tokitoh, T. Matsumoto, K. Manmaru, and R. Okazaki, J. Am. Chem. Soc., 115, 8855 (1993).
3. b) T. Matsumoto, N. Tokitoh, and R. Okazaki, Angew. Chem. Int. Ed. EngI., 33, 2316 (1994).
4. H. Suzuki, N. Tokitoh, S. Nagase, and R. Okazaki, J. Am. Chem. Soc., 116, 11578 (1994).
5. N. Tokitoh, T. Matsumoto, and R, Okazaki, Chem. Lett., 1995, 1087.
6. e) M. Saito, N. Tokitoh, and R. Okazaki, Organometallics, 15, 4531 (1996).
7. f) N. Kano, N. Tokitoh, and R. Okazaki, Chem. Lett., 1997, 277.
8. g) N. Tokitoh, T. Matsumoto, and R. Okazaki, J. Am. Chem. Soc., 119, 2337 (1997).
9. h) M. Saito, N. Tokitoh, and R. Okazaki, J. Am. Chem. Soc., 119, 11124 (1997). and references cited therein.
10. R. Okazaki, N. Tokitoh, and T. Matsumoto, in "Synthetic Methods of Organometallic and Inorganic Chemistry", ed by N. Auner and U. Klingebiel, Thieme, New York, (1996) Vol. 2, pp. 260-269.
11. a) G. H. Miracle, J. L. Ball, D. R. Powell, and R. West, J. Am. Chem. Soc., 115, 11598 (1993).
12. b) M. Trommer, G. E. Miracle, E. Eichler, D. R. Powell, and R. West, Organometallics, 16, 5737 (1997).
13. Quite recently, West et al. reported the synthesis and structure of stable l-germaallenes independently. See. B. E. Eichler, D. R. Powell, and R. West, Organometallics, 17, 2147 (1998).
14. K. Kishikawa, N. Tokitoh, and R. Okazaki, Organometallics, 16, 5127 (1997).
15. K. Kishikawa, N. Tokitoh, and R. Okazaki, Chem. Lett., 1998, 239.
16. H. Ramdane, H. Ranaivonjatovo, and J. Escudié, Organometallics, 15, 3070 (1996).
17. 6.