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Although we examined the effect of α on the simulation curve, α was almost insensitive to the shape of the curve. On the other hand, the shape of the coverage-[dye] curve was highly dependent on N. Therefore, it is worth noting that with the present approach it might in general be difficult to fit a steep coverage[dye] curve.
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31
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L aggregates had a two-dimensional structure at the interface as often discussed in the literature (ref. 15). Actually, the effect of the dimensionality factor on the shape of the simulation curve was very small when N < 10.
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A ladder structure of J aggregates has also been proposed. However, it is less suitable to explain the shift energy of the aggregate as compared to the present discussion based on the staircase or brickstone arrangement as discussed in ref. 32.
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