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Volumn 15, Issue 21, 1999, Pages 7372-7377

Electroenzyme-catalyzed oxidation of styrène and cis-β-methylstyrene using thin films of cytochrome P450cam and myoglobin

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHARGE TRANSFER; ELECTROCHEMISTRY; ENZYMES; EPOXY RESINS; HYDROGEN PEROXIDE; OXIDATION; PLASTIC FILMS; POLYELECTROLYTES; REACTION KINETICS; STEREOCHEMISTRY; SURFACE ACTIVE AGENTS;

EID: 0033204150     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la990685k     Document Type: Article
Times cited : (96)

References (58)
  • 13
    • 0002529110 scopus 로고
    • Guengerich, F. P., Ed.; CRC Press: Boca Raton, FL
    • (a) Yang, G. S.; Lu, A. Y. H. In Mammalian Cytochromes P450; Guengerich, F. P., Ed.; CRC Press: Boca Raton, FL, 1987; Vol. 2, pp 1-17.
    • (1987) Mammalian Cytochromes P450 , vol.2 , pp. 1-17
    • Yang, G.S.1    Lu, A.Y.H.2
  • 14
    • 0343163279 scopus 로고
    • Guengerich, F. P., Ed.; CRC Press: Boca Raton, FL
    • (b) Nelson, S. D.; Harvison, P. J. In Mammalian Cytochromes P450; Guengerich, F. P., Ed.; CRC Press: Boca Raton, FL, 1987; Vol. 2, pp 19-79.
    • (1987) Mammalian Cytochromes P450 , vol.2 , pp. 19-79
    • Nelson, S.D.1    Harvison, P.J.2
  • 47
    • 85088810170 scopus 로고    scopus 로고
    • note
    • 27
  • 48
    • 33749192546 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of Connecticut, Storrs, CT
    • Zu, X. Ph.D. Thesis, University of Connecticut, Storrs, CT, 1998.
    • (1998)
    • Zu, X.1
  • 49
    • 33749217866 scopus 로고    scopus 로고
    • note
    • Cyt P450cam was stored at -78°C in the camphor-bound form. Similar turnover numbers were obtained whether camphor was removed before the experiment or not, so nearly all experiments were done without removing camphor. During film preparation or in solution, since no camphor was present, the enzyme is likely to end up in the camphor-free form.
  • 50
    • 33749220004 scopus 로고    scopus 로고
    • note
    • Minor oxidation products as reported in refs 14, 15, and 23b were also found at 2% of total products.
  • 53
    • 33749208618 scopus 로고    scopus 로고
    • note
    • (b) The films refered to here were 1-4 μm thick to obtain sufficient optical absorbance. Films in the present study were 11-12 nm (see Table 1, footnote a).
  • 58
    • 33749233284 scopus 로고    scopus 로고
    • note
    • Also, participation of Superoxide radical, a possible decomposition product of a ferric-peroxo intermediate,5 cannot be ruled out at present.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.