Initiation effects in the living cationic polymerization of isobutylene

Macromolecules

Volumn 32, Issue 21, 1999, Pages 7003-7011

  Storey, Robson F ^a   Donnalley, Andrew B ^a  

^a Virginia Polytechnic Institute and State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CATIONIC POLYMERIZATION; CHLORINE; HEPTANE; INITIATORS (CHEMICAL); IONIZATION; LIGHT ABSORPTION; MONOMERS; ORGANIC SOLVENTS; RATE CONSTANTS; THERMAL EFFECTS; TITANIUM COMPOUNDS;

LIGHT CONDUIT TECHNOLOGY; LIVING CATIONIC POLYMERIZATION;

POLYBUTENES;

EID: 0033203680     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9901700     Document Type: Article

References (25)

1. Roth, M.; Patz, M.; Fréter, H.; Mayr, H. Macromolecules 1997, 30, 722.
2. Mayr, H.; Roth, M.; Deters, M. Macromolecules 1997, 30, 3965.
3. Brown, H. C.; Berneis, H. L. J. Am. Chem. Soc. 1953, 75,10.
4. Roth, M.; Mayr, H. Macromolecules 1996, 29, 6104.
5. Mayr, H.; Roth, M.; Faust, R. Macromolecules 1996,29,6110.
6. Storey, R. F.; Donnalley, A. B. ACSDiu. Polym. Chem., Polym. Prepr. 1998, 39 (1), 329.
7. Storey, R. F.; Donnalley, A. B., manuscript in preparation.
8. Storey, R. F.; Choate, K. R., Jr. Macromolecules 1997, 30, 4799.
9. Fodor, Z.; Bae, Y. C.; Faust, R. Macromolecules 1998, 31, 4439.
10. Puskas, J. E.; Lanzendörfer, M. G. Macromolecules 1998,31, 8684.
11. Puskas, J. E.; Lanzendörfer, M. G.; Patten, W. E. Polym. Bull. 1998, 40, 55.
12. Storey, R. F.; Maggio, T. L. ACS D'w. Polym. Chem., Polym. Prepr. 1998, 39 (2), 778.
13. Storey, R. F.; Donnalley, A. B.; Maggio, T. L. Macromolecules 1998, 31, 1523.
14. Storey, R. F.; Maggio, T. L., manuscript in preparation.
15. Curry, C. L. Ph.D. Dissertation, The University of Southern Mississippi, in preparation.
16. Storey, R. F.; Curry, C. L.; Brister, L. B. Macromolecules 1998, 31, 1058.
17. -1; e.g., methylcyclohexane is superior to hexane in this regard since it has a much smaller absorbance at this wavenumber. For methylcyclohexane, typical relative absorbance values are 0.03 prior to monomer addition, 1.62 immediately after addition of l M IB, and 0.00 at very long reaction times. Use of 0.03 as the reference absorbance yields an error in the calculated conversion of 0.03 x 100%/(1.62 - 0.03) = 1.97c.
18. Puskas, J.; Kaszas, G.; Kennedy, J. P.; Kelen, T.; Tudos, F. J. Macromol. Sei., Chem. 1983, A18, 1229.
19. Storey, R. F.; Shoemake, K. A. ACS Div. Polym. Chem., Polym. Prepr. 1995, 36 (2), 304.
20. Puskas, J. E.; Kaszas, G.; Litt, M. Macromolecules 1991,24, 5278.
21. Storey, R. F.; Chisholm, B. J.; Brister, L. B. Macromolecules 1995, 28, 4055.
22. Matyjaszewski, K.; Pugh, C. In Cationic Polymerization: Mechanisms, Synthesis, and Applications; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; p 205.
23. Mayr, H. Makromol. Chem., Macromol. Symp. 1988,13/14, 43.
24. Ivan, B.; Kennedy, J. P. Macromolecules 1990, 23, 2880.
25. Russell, R; Moreau, M.; Charleux, B.; Vairon, J.-P.; Matyjaszewski, K. Macromolecules 1998, 31, 3775.