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Volumn 1, Issue 15, 1999, Pages 3689-3695

Experimental and ab initio spectra of the persistent carbocation generated upon adsorption of vinylanisole in acid zeolites

Author keywords

[No Author keywords available]

Indexed keywords

ANISOLE DERIVATIVE; ION; ZEOLITE;

EID: 0033179027     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/a903291f     Document Type: Article
Times cited : (11)

References (89)
  • 1
    • 4243433202 scopus 로고    scopus 로고
    • Ethical guidelines to publication of chemical research
    • 1 See the 'Ethical Guidelines to Publication of Chemical Research' in J. Org. Chem., 1996, 61, 27A.
    • (1996) J. Org. Chem. , vol.61
  • 58
    • 0009569366 scopus 로고    scopus 로고
    • -1
    • -1.
  • 60
    • 0009570329 scopus 로고    scopus 로고
    • note
    • 60 It has been considered that 1-anisylethyl cation has two extreme conformers in which the methyl groups of the methoxy and ethyl substituents in the para positions are either cis or trans. In this regard the optimized geometry shown in Fig. 3 corresponds to the trans conformation.
  • 80
    • 0009569231 scopus 로고    scopus 로고
    • We have established that steady lamp photolysis of ZSM-5 samples containing 1 produces a shift in their absorption and emission spectra compatible with cis-trans isomerization of the allyl system from the E, E-1 to the E, Z-1 stereoisomer. See ref. 13
    • 80 We have established that steady lamp photolysis of ZSM-5 samples containing 1 produces a shift in their absorption and emission spectra compatible with cis-trans isomerization of the allyl system from the E, E-1 to the E, Z-1 stereoisomer. See ref. 13.
  • 81
    • 0009611784 scopus 로고    scopus 로고
    • B3LYP has been shown to be a very accurate ab initio method to predict IR spectra. See, among many others, the following three references
    • 81 B3LYP has been shown to be a very accurate ab initio method to predict IR spectra. See, among many others, the following three references.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.