(2-Pyridyldimethylsilyl)methyl lithium as a novel hydroxymethylating reagent

Tetrahedron Letters

Volumn 40, Issue 30, 1999, Pages 5537-5540

  Itami, Kenichiro ^a   Mitsudo, Koichi ^a   Yoshida, Jun ichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

(2 PYRIDYLDIMETHYLSILYL)METHYL LITHIUM; ALDEHYDE; BROMIDE; KETONE DERIVATIVE; LITHIUM DERIVATIVE; REAGENT; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; METHYLATION; SYNTHESIS;

EID: 0033165956     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01028-X     Document Type: Article

References (21)

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20. 3): δ -3.0, -2.7, 28.1, 70.0, 123.1, 125.2, 126.4, 128.0, 129.3, 135.0, 148.0, 148.9, 166.5.
21. 4 and subsequent silica gel chromatography (hexane:EtOAc=1:1 to 1:2) afforded phenyl-1,2-ethanediol (66 mg, 96%) as a white solid.