[RuCl2(COD)]n: A simplified source of Ru(II)-catalysts for the asymmetric hydrogenation of functionalized ketones

Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry

Volumn 2, Issue 3, 1999, Pages 175-179

  Guerreiro, Patricio ^a   Cano De Andrade, Maria Cristina ^a   Henry, Jean Christophe ^a   Tranchier, Jean Philippe ^a   Phansavath, Phannarath ^a   Ratovelomanana Vidal, Virginie ^a   Genêt, Jean Pierre ^a   Homri, Tarek ^b   Touati, Ali Rhida ^b   Ben Hassine, Bechir ^b  

^a PSL RESEARCH UNIVERSITY   (France)

^b FACULTÉ DES SCIENCES DE MONASTIR   (Tunisia)

Author keywords

Enantioselective hydrogenation; Ruthenium catalyst

Indexed keywords

EID: 0033098162     PISSN: 13871609     EISSN: None     Source Type: Journal    
DOI: 10.1016/s1387-1609(99)80061-9     Document Type: Article

References (28)

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27. n (2.8 mg) were placed in a 10 mL glass reactor introduced in a steel autoclave and purged with argon. 2 mL of MeOH (degassed by 3 cycles of vacuum/argon at room temperature) were added. To this suspension was added the prochiral ketone (1 mmol) and the mixture was hydrogenated.
28. We are grateful to Dr. E. Broger and Dr. R. Schmid (Hoffman La Roche) for samples of (R)-(+)-MeO-Biphep = (R)-(+)-6,6′-Dimethoxy-2,2′-bis(diphenyl-phosphino)-1,1′-biphenyl and (S)-(-)-MeO-Biphep.