Construction of the 6-azabicyclo[3.2.1]octane ring system via higher- order cycloaddition; formal total synthesis of (±)-peduncularine

Synlett

Volumn , Issue SPEC. ISS., 1999, Pages 860-862

  Rigby, James H ^a   Meyer, J Hoyt ^a  

^a WAYNE STATE UNIVERSITY   (United States)

Author keywords

Azabicyclo 3.2.1 octane; Chromium(0) promoted; Higher order cycloaddition; Peduncularine; 6 +2 cycloaddition

Indexed keywords

6 AZABICYCLO[3.2.1]OCTANE DERIVATIVE; ALKALOID; ALKENE DERIVATIVE; BICYCLO COMPOUND; CHROMIUM; CYCLOALKANE DERIVATIVE; ISOCYANIC ACID DERIVATIVE; PEDUNCULARINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CYCLIZATION; PLANT; REACTION ANALYSIS; SYNTHESIS;

EID: 0033015287     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-3083     Document Type: Article

References (24)

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24. 3) δ 1.14 (d, J = 7, Hz, 3H); 1.15 (d, J = 7 Hz, 3H); 2.36 (m, 2H); 2.85 (m, 1H); 3.97 (m, 1H); 4.36 (septet, J = 7 Hz, 1H); 5.18 (dd, J = 5, 5 Hz, 1H); 5.84 (m, 1H); 5.94 (m, 1H); 8.05 (d, J = 0.9 Hz, 1H).