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Volumn 61, Issue 19, 1996, Pages 6480-6481

Stille couplings with fluorous tin reactants: Attractive features for preparative organic synthesis and liquid-phase combinatorial synthesis

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Indexed keywords


EID: 0000361705     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo961309x     Document Type: Article
Times cited : (141)

References (26)
  • 2
    • 85033846610 scopus 로고    scopus 로고
    • U.S. Patent no. 5,463,082, 1995
    • (b) Horváth, I. T.; Rabái, J., U.S. Patent no. 5,463,082, 1995.
    • Horváth, I.T.1    Rabái, J.2
  • 15
    • 85033855236 scopus 로고    scopus 로고
    • note
    • For the purposes of combinatorial synthesis, a "reactant" provides a variable piece to the product library.
  • 21
    • 85033848029 scopus 로고    scopus 로고
    • note
    • 14 (bp 56 °C).
  • 22
    • 85033869359 scopus 로고    scopus 로고
    • note
    • Most of the residual 10-20% remained in the organic phase. If desired, this can be removed by washing with FC-72, as shown in the preparative procedure.
  • 23
    • 43949163594 scopus 로고
    • Significant amounts of cross-coupled products (estimated 25-50%) were produced with 4-nitrophenyl triflate and bromide and with iodobenzene; however, yields of pure products were not determined. These results parallel results with normal 2-pyridyltin reagents. See: Gronowitz, S; Björk, P.; Malm, J.; Hörnfeldt, A.-B. J. Organomet. Chem. 1993, 460, 127.
    • (1993) J. Organomet. Chem. , vol.460 , pp. 127
    • Gronowitz, S.1    Björk, P.2    Malm, J.3    Hörnfeldt, A.-B.4
  • 26
    • 85033834855 scopus 로고    scopus 로고
    • note
    • 2 or toluene are ≥97/3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.