Unexpected bell-shaped effect of the ligand on the rate of the oxidative addition to palladium(0) complexes generated in situ from mixtures of Pd(dba)2 and para-substituted triarylphosphines

Inorganica Chimica Acta

Volumn 273, Issue 1-2, 1998, Pages 76-84

  Amatore, Christian ^a   Jutand, Anny ^a   Meyer, Gilbert ^a  

^a ECOLE NORMALE SUPÉRIEURE   (France)

Author keywords

Aryl halides; Oxidative addition: Triarylphosphine complexes; Palladium complexes

Indexed keywords

ELECTRONS; LIGANDS; MIXTURES; ORGANOMETALLICS; PHOSPHORUS COMPOUNDS;

ANTAGONIST EFFECTS; ARYL HALIDES; HAMMETT CORRELATION; INTRINSIC REACTIVITY; OXIDATIVE ADDITIONS; PALLADIUM COMPLEXES; TRIARYLPHOSPHINES; TRIPHENYLPHOSPHINES;

PALLADIUM COMPOUNDS;

EID: 0001787805     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)06015-5     Document Type: Article

References (22)

1. R.F. Heck, Palladium Reagents in Organic Synthesis, Academic Press, London, 1985.
2. J. Tsuji, Palladium Reagents and Catalysis: Innovations in Organic Chemistry, Wiley, Chichester, 1995.
3. J.-L. Malleron, J.-C. Fiaud and J-Y. Legros, Handbook of Palladium-Catalyzed Organic Reactions. Synthetic Aspects and Catalytic Cycles, Academic Press, London, 1997.
4. M. Kumada, Pure Appl. Chem., 52 (1980) 669.
5. E.I. Negishi, Acc. Chem. Res., 15 (1982) 340.
6. J.K. Stille, Angew. Chem., Int. Ed. Engl., 25 (1986) 508.
7. R.F. Heck, Org. React., 27 (1982) 345.
8. A. de Mejeire and F.E. Meyer, Angew. Chem., Int. Ed. Engl., 33 (1994) 2379.
9. B.M. Trost, Angew. Chem., Int. Ed. Engl., 28 (1989) 1173.
10. C. Amatore, A. Jutand, F. Khalil, M.A. M'Barki and L. Mottier, Organometallics, 12 (1993) 3168.
11. C. Amatore, G. Broeker, A. Jutand and F. Khalil, J. Am. Chem. Soc., 119 (1997) 5176.
12. J.K. Stille and K.S.Y. Lau, Acc. Chem. Res., 10 (1977) 434.
13. C. Amatore, E. Carré, A. Jutand and M.A. M'Barki, Organometallics, 14 (1995) 1818.
14. Y. Takahashi, Ts. Ito and Y. Ishi, J. Chem. Soc., Chem. Commun., (1970) 1065.
15. D.T. Rosevear and F.G. Stone, J. Chem. Soc. A, (1968) 164.
16. P. Fitton, M.P. Johnson and J.E. Mc Keon, J. Chem. Soc., Chem. Commun., (1968) 6.
17. W.A. Herrmann, W.R. Thiel, C. Broßmer, K. Ötele, T. Priermeier and W. Scherer, J. Organomet. Chem., 461 (1993) 51.
18. A.J. Bard and L.R. Faulkner, Electrochemical Methods, Wiley, New York, 1980, p. 443.
19. B.E. Mann and A. Musco. J. Chem. Soc., Dalton Trans., (1968) 1530.
20. C.A. Tolman, J. Chem. Rev., 77 (1977) 313.
21. J.F. Fauvarque, F. Pflüger and M. Troupel, J. Organomet. Chem., 208 (1981) 419.
22. C. Amatore and F. Pflüger, Organometallics, 9 (1990) 2276.