A new diastereoselective synthesis of enantiomerically pure 1,2-oxazine derivatives by addition of lithiated methoxyallene to chiral nitrones

Synlett

Volumn , Issue 5, 1999, Pages 632-634

  Schade, Wolfgang ^a   Reissig, Hans Ulrich ^a  

^a DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

1,2 oxazine; Allenyl hydroxylamine; Methoxyallene; Nitrone

Indexed keywords

1,2 OXAZINE DERIVATIVE; 3,6 DIHYDRO 2H 1,2 OXAZINE; ALUMINUM CHLORIDE; HYDROXYLAMINE; LITHIATED METHOXYALLENE; NITROGEN DERIVATIVE; NITRONE; ORGANOLITHIUM COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; CYCLIZATION; DIASTEREOISOMER; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0032963762     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2662     Document Type: Article

References (34)

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33. The assignment is now proved by an X-ray crystal structure analysis of a subsequent product of anti-6b.
34. W. Schade, T. Watanabe, R. Pulz, H.-U. Reissig, manuscript in preparation.