New results on the functionalization of terminal alkenes by cross- metathesis reactions

Synlett

Volumn , Issue 5, 1999, Pages 557-558

  Blanco, Olga M ^a   Castedo, Luis ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

Allylic bromides; Cross metathesis; Ruthenium

Indexed keywords

ALKENE; BENZENE; BROMIDE; RUTHENIUM;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0032940083     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2676     Document Type: Article

References (13)

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12. 13C NMR, IR and mass spectrometry. E/Z isomer ratios in the crude final reaction mixture were calculated from 500 MHz NMR integrals, and the major isomer was identified from the coupling constants of the olefinic hydrogens.
13. For instance, refluxing allylalcohol in dichloromethane for 16 h in the presence of Ru gave the dimer in 90% yield.