Model for random hydrolysis and end degradation of linear polysaccharides: Application to the thermal treatment of mannan in solution

Industrial and Engineering Chemistry Research

Volumn 38, Issue 8, 1999, Pages 2919-2926

  Nattorp, Anders ^a   Graf, Martin ^a   Spühler, Christian ^a   Renken, Albert ^a  

^a EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; DEGRADATION; HEAT TREATMENT; HYDROLYSIS; MATHEMATICAL MODELS; PH EFFECTS; POLYMERIZATION; RATE CONSTANTS; SOLUTIONS; TEMPERATURE;

ARRHENIUS RELATIONSHIP; FIRST ORDER DEPOLYMERIZATION;

POLYSACCHARIDES;

MANNAN; MONOSACCHARIDE; OLIGOSACCHARIDE; POLYSACCHARIDE;

ARTICLE; CHEMICAL REACTION KINETICS; DEGRADATION; HEAT TREATMENT; HYDROLYSIS; MATHEMATICAL MODEL; REACTION ANALYSIS;

EID: 0032874642     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie990034j     Document Type: Article

References (33)

1. Bradbury, A. G. W.; Halliday, D. J. Chemical structures of green coffee bean polysaccharides. J. Agric. Food Chem. 1990, 38, 389.
2. Monro, J. A.; Harding, W. R.; Russell, C. E. Dietary fibre of coconuts from a pacific atoll: soluble and insoluble components in relation to maturity. J. Sci. Food Agric. 1985, 36, 1013.
3. Meier, H. On the structure of cell walls and cell wall mannans from ivory nuts and from dates. Biochim. Biophys. Acta 1968, 28, 229.
4. Chanzy, H. D.; Grosrenaud, A.; Vuong, R.; Mackie, W. The crystalline polymorphism of mannan in plant cell walls and after recrystallisation. Planta 1984, 161, 320.
5. Whistler, R. L. Solubility of polysaccharides and their behaviour in solution. Adv. Chem. Ser. 1973, 117, 242.
6. Lüttge, U.; Kluge, M.; Bauer, G. Botanique; Tec et doc Lavoisier: Paris, 1992.
7. Garves, K. Temperature, salt, and acidity effects on the hydrolysis of cellulose dissolved in concentrated acids. Cellulose Chem. Technol. 1996, 30, 3.
8. Sasaki, M.; Kabyemela, B.; Adschiri, T.; Malaluan, R.; Hirose, S.; Takeda, N.; Arai, K. Cellulose hydrolysis in subcritical and supercritical water. J. Supercrit. Fluids 1998, 13, 261.
9. Moiseev, Y. V.; Zaikov, G. E. Chemical Resistance of Polymers in Aggressive Media; Consultants Bureau: New York, 1987.
10. Bobleter, O.; Bonn, G. The hydrothermolysis of cellobiose and its reaction product D-glucose. Carbohydr. Res. 1983, 124, 185.
11. Coultate, T. P. Food, the Chemistry of its Components; The Royal Society of Chemistry: London, 1989.
12. Bunn, H. F.; Higgins, P. J. Reaction of monosaccharides with proteins: possible evolutionary significance. Science 1981, 273, 222.
13. Kabyemela, B. M.; Takigawa, M.; Adschiri, T.; Malaluan, R. M.; Arai, K. Mechanism and kinetics of cellobiose decomposition in sub- and supercritical water. Ind. Eng. Chem. Res. 1998, 37, 357.
14. Kamiyama, Y.; Sakai, Y. Rate of hydrolysis of xylo-oligosaccharides in dilute sulfuric acid. Carbohydr. Res. 1979, 73, 151.
15. Weintraub, M. S.; French, D. Acid hydrolysis of (1 → 4)-alpha-D-glucans. Carbohydr. Res. 1970, 15, 251.
16. Basedow, A. M.; Ebert, K. H.; Ederer, H. J. Kinetic studies on the acid hydrolysis of dextran. Macromolecules 1978, 11, 774.
17. Pinto, J. H. Q.; Kalaguine, S. A. Monte Carlo analysis of glucosidic bonds in polysaccharides. AIChE J. 1991, 37, 905.
18. Kim, M. H.; Kim, C. S.; Lee, H. W.; Kim, K. Temperature dependence of dissociation constants for formic acid in aqueous solutions up to 175 °C. J. Chem. Soc., Faraday Trans. 1996, 92, 4951.
19. Fried, J. R. Polymer Science and Technology; Prentice-Hall: Englewood Cliffs, NJ, 1995.
20. Ballauff, M.; Wolf, B. A. Degradation of chain molecules. 2. Thermodynamically induced shear degradation of dissolved polystyrene. Macromolecules 1984, 17, 209.
21. Ballauff, M.; Wolf, B. A. Thermodynamically induced shear degradation. Advances in Polymer Science 85: Polymer Physics; Springer-Verlag: New York, 1988.
22. Jellinek, H. H. G.; White, G. The degradation of long-chain molecules by ultrasonic waves. I. Theoretical. J. Polym. Sci. 1951, VI, 745.
23. Mostafa, M. A. K. Degradation of addition polymers by ultrasonic waves. J. Polym. Sci. 1956, XXII, 535.
24. Schaaf, E.; Zimmermann, H. Thermogravimetrische Untersuchung des thermischen und thermooxydativen Abbaus von Polyäthylenterephthalat. Faserforsch. Textiltech. 1974, 25, 434.
25. Kuhn, W. Ueber die Kinetik des Abbaues hochmolekularer Ketten. Ber. Chem. Dtsch. Ges. 1930, 63, 1503.
26. Guiata, M.; Chiantore, O.; Luda, M. P. Monte Carlo simulations of polymer degradations. 1. Degradations without volatilization. Macromolecules 1990, 23, 2087.
27. Lowry, G. G. Markov Chains and Monte Carlo Calculations in Polymer Science; Marcel Dekker: New York, 1970.
28. Ziff, R. M.; McGrady, E. D. Kinetics of polymer degradation. Macromolecules 1986, 19, 2513.
29. Gear, C. W. Numerical Initial Value Problems in Ordinary Differential Equations; Prentice-Hall: Englewood Cliffs, NJ, 1971.
30. Steiner, E.; Rey, T.; McCroskey, M. SimuSolv Reference Guide; Dow Co.: Midland, MI, 1990.
31. Kabyemela, B. M.; Adschiri, T.; Malaluan, R. M.; Arai, K. Kinetics of glucose epimerization and decomposition in subcritical and supercritical water. Ind. Eng. Chem. Res. 1997, 36, 1552.
32. Bobleter, O.; Pape, G. Der hydrothermale Abbau von Glucose. Monath. Chem. 1968, 99, 1560.
33. Feather, M. S.; Harris, J. F. The acid-catalysed hydrolysis of glycopyranosides. J. Org. Chem. 1965, 30, 153.