Oxidation and hydrolysis of lactic acid in near-critical water

Industrial and Engineering Chemistry Research

Volumn 38, Issue 7, 1999, Pages 2599-2606

  Li, Lixiong ^a   Portela, Juan R ^b   Vallejo, David ^a,c,d   Gloyna, Earnest F ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b UNIVERSITY OF CÁDIZ   (Spain)

^c UT SCWO Projects ^*

^d BURNS AND MCDONNELL   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ALDEHYDES; CARBON; CARBON MONOXIDE; HYDROLYSIS; INORGANIC ACIDS; MATHEMATICAL MODELS; METHANE; OXIDATION; SUPERCRITICAL FLUIDS; WATER;

ACETALDEHYDE; HYDROTHERMAL REACTION; LACTIC ACID; TOTAL ORGANIC COMPOUNDS;

REACTION KINETICS;

LACTIC ACID; WATER;

ARTICLE; HIGH TEMPERATURE PROCEDURES; HYDROLYSIS; ION PAIR CHROMATOGRAPHY; KINETICS; OXIDATION; PRESSURE; REACTION ANALYSIS; SUPERCRITICAL FLUID EXTRACTION; TOTAL ORGANIC CARBON;

EID: 0032793616     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie980520r     Document Type: Article

References (44)

1. Modell, M. Gasification and Liquefaction of Forest Products in Supercritical Water. In Fundamentals of Thermochemical Biomass Conversion; Overend, R. P., Milne, T. A., Mudge, L. K., Ed.; Elsevier Applied Science Publ.: New York, 1985; Chapter 6.
2. Xu, X.; Matsumura, Y.; Stenberg, J.; Antal, M. J., Jr. Catalytic Gasification of Biomass and Destruction of Waste Materials in Supercritical Water. Ind. Eng. Chem. Res. 1996, 35 (8), 2522.
3. Klein, M. T.; Torry, L. A.; Wu, B. C.; Townsend, S. H.; Paspeck, S. C. Hydrolysis in Supercritical Water: Solvent Effects as a Probe of the Reaction Mechanism. J. Supercrit. Fluids 1990, 3 (4), 222.
4. Sasaki, M.; Kabyemela, B.; Malaluan, R.; Hirose, S.; Takeda, N.; Adschiri, T.; Arai, K. Cellulose Hydrolysis in Subcritical and Supercritical Water. J. Supercrit. Fluids 1998, 13, 261.
5. Modell, M. Supercritical Water Oxidation. In Standard Handbook of Hazardous Waste Treatment and Disposal; Freeman, H. M., Ed.; McGraw-Hill: New York, 1989; Chapter 8.
6. Shaw, R. W.; Brill, T. B.; Eckert, C. A.; Franck, E. U. Supercritical Water-A Medium for Chemistry. Chem. Eng. News 1991, Dec., 26.
7. Tester, J. W.; Holgate, H. R.; Armellini, F. J.; Webley, P. A.; Killilea, W. R.; Hong G. T.; Barner, H. E. Supercritical Water Oxidation Technology: A Review of Process Development and Fundamental Research. In Emerging Technologies for Hazardous Waste Management III; Tedder, D. W., Pohland, F. G., Eds.; ACS Symposium Series 518; American Chemical Society: Washington, DC, 1992; Chapter 3.
8. Gloyna, E. F.; Li, L. Supercritical Water Oxidation: An Engineering Update. Waste Management 1993, 13 (5-7), 379.
9. Savage, P. E.; Gopalan, S.; Mizan T. I.; Martino, C. J.; Brock. E. E. Reactions at Supercritical Conditions: Applications and Fundamentals. AIChE J. 1995, 41 (7), 1723.
10. Mok, W. S.-L.; Antal, M. J. Formation of Acrylic Acid from Lactic Acid in Supercritical Water. J. Org. Chem. 1989, 54 (19), 4596.
11. Xu, X.; Almeida, C. D.; Antal, M. J., Jr. Mechanism and Kinetics of the Acid-Catalyzed Dehydration of Ethanol in Supercritical Water. J. Supercrit. Fluids 1990, 3 (4), 228.
12. Bjerre, A. B.; Sorensen, E. Thermal Decomposition of Dilute Aqueous Formic Acid Solutions. Ind. Eng. Chem. Res. 1992, 31 (6), 1574.
13. Yu, J.; Savage, P. E. Decomposition of Formic Acid under Hydrothermal Conditions. Ind. Eng. Chem. Res. 1998, 37 (1), 2.
14. Gupta, R.; Johnston, K. P. Ion Hydration in Supercritical Water. Ind. Eng. Chem. Res. 1994, 33, 2819.
15. Xiang, T.; Johnston, K. P. Acid-Base Behavior of Organic Compounds in Supercritical Water. J. Phys. Chem. 1994, 98 (32), 7915.
16. Mishra, V. S.; Mahajani, V. V.; Joshi, J. B. Wet Air Oxidation. Ind. Eng. Chem. Res. 1995, 34 (1), 2.
17. Gloyna, E. F.; Li, L. Supercritical Water Oxidation for Remediation of Wastewaters and Sludges, in Encyclopedia of Environmental Analysis and Remediation; Meyers, R. A., Ed.; John Wiley & Sons: New York, 1998.
18. Vallejo, D. F. Synthesis of Acetic Acid from Nontraditional Feedstocks in Subcritical and Supercritical Water Oxidation. M.S. Thesis, Civil Engineering Department, The University of Texas at Austin, Austin, TX, 1996.
19. Li, L.; Gloyna, E. F. Separation of Ionic Species under Supercritical Water Conditions. Presented at the Tenth Symposium on Separation Science and Technology for Energy Applications, Gatlinburg, TN, Oct 20-24, 1997.
20. Li, L.; Chen, P.; Gloyna, E. F. Generalized Kinetic Model for Wet Oxidation of Organic Compounds. AIChE J. 1991, 37(11), 1687-1697.
21. Ding, Z. Y.; Frisch, M. A.; Li, L.; Gloyna, E. F. Catalytic Oxidation in Supercritical Water. Ind. Eng. Chem. Res. 1996, 35 (10), 3257.
22. Lee, D. S. Supercritical Water Oxidation of Acetamide and Acetic Acid. Ph.D. Dissertation, Civil Engineering Department, The University of Texas at Austin, Austin, TX, 1990.
23. Rice, S. F.; Steeper, R. R.; LaJeunesse, C. A. Destruction of Representative Navy Wastes Using Supercritical Water Oxidation; Sandia Report SAND94-8203·UC-402, Sandia National Laboratories: Livermore, CA, 1993.
24. Li, L.; Chen, P.; Gloyna, E. F. Pilot-Plant Validation of Global Kinetic Models for Supercritical Water Oxidation. In Chemical Oxidation: Technology for the Nineties; Eckenfelder, W. W., Bowers, A. F., Roth, J. A., Eds.; Technomic Publishing Co.: Lancaster, PA, 1997; Vol. 4, p 219.
25. Meyer, J. C.; Marrone, P. A.; Tester, J. W. Acetic Acid Oxidation and Hydrolysis in Supercritical Water. AIChE J. 1995, 41 (9), 2108.
26. Foussard, J.; Debellefontaine, H.; Besombes-Vailhe, J. Efficient Elimination of Organic Liquid Wastes: Wet Air Oxidation. J. Environ. Eng. 1989, 115 (2), 367.
27. Wilmanns, E. G. Supercritical Water Oxidation of Volatile Acids. M.S. Thesis, Civil Engineering Department, The University of Texas at Austin, Austin, TX, 1990.
28. Crain, N. E. Supercritical Water Oxidaiotn Kinetics of Propellant Simulant. Ph.D. Dissertation, Civil Engineering Department, The University of Texas at Austin, Austin, TX, 1994.
29. Baillod, C. R.; Faith, B. M.; Masi, O.; Fate of Specific Pollutants During Wet Oxidation and Ozonation. Environ. Progress 1982, 1 (3), 217.
30. Wightman, T. J. Studies in Supercritical Wet Air Oxidation. M.S. Thesis, University of California at Berkeley, Berkeley, CA, 1981.
31. Shende, R. V.; Mahajani, V. V. Kinetics of Wet Oxidation of Formic Acid and Acetic Acid. Ind. Eng. Chem. Res. 1997, 36 (11), 4809.
32. Shende, R. V.; Mahajani, V. V. Kinetics of Wet Air Oxidation of Glyoxalic Acid and Oxalic Acid. Ind. Eng. Chem. Res. 1994, 33 (12), 3125.
33. Datta, R.; Tsai, S. P. Lactic-Acid Production and Potential Uses: A Technology and Economics Assessment. ACS Symp. Ser. 1997, 666, 224.
34. Lira, C. T.; McCrackin, P. J. Conversion of Lactic Acid to Acrylic Acid in Near-Critical Water. Ind. Eng. Chem. Res. 1993, 32 (11), 2608.
35. Gunter, G. C.; Crachin, R.; Tam, M. S.; Jackson, J. E.; Miller, D. J. FTIR and P-31-NMR Spectroscopic Analysis of Surface Species in Phosphate-Catalyzed Lactic-Acid Conversion. J. Catal. 1996, 164 (1), 207.
36. Tam, M. S.; Gunter, G. C.; Craciun, R.; Miller, D. J.; Jackson, J. E. Reaction and Spectroscopic Studies of Sodium-Salt Catalysts for Lactic-Acid Conversion. Ind. Eng. Chem. Res. 1997, 36 (9) 3505.
37. Croiset, E.; Rice, S F.; Hanush, R. G Hydrogen-peroxide Decomposition in Supercritical Water. AIChE J. 1997, 43 (9), 2343.
38. 2 in Supercritical Water. Ind. Eng. Chem. Res. 1998, 37 (5) 1755.
39. Bourhis, A. L.; Swallow, K. C., Hong, G. T.; Killilea, W. R. The Use of Rate Enhancers in Supercritical Water Oxidation. In Innovations in Supercritical Fluids Science and Technology; Hutchenson, K. W., Foster, N. R., Eds.; ACS Symposium Series; American Chemical Society: Washington, DC, 1995; Vol. 508, p 338.
40. Cutler, A. H.; Antal, M. J., Jr.; Jones, M., Jr. A Critical Evaluation of the Plug-Flow Idealization of Tubular-Flow Reactor Data. Ind. Eng. Chem. Res. 1988, 27, 691.
41. Helling, R. K. Oxidation of Simple Compounds and Mixtures in Supercritical Water: Carbon Monoxide, Ammonia and Ethanol. Ph.D. Dissertation, MIT, Cambridge, MA, 1986.
42. Foussard, J. Study on Aqueous Phase Oxidation at Elevated Temperatures and Pressures. Ph.D. Dissertation, National Institute of Applied Science, Toulouse, France, 1983.
43. Holgate, H. R.; Webley, P. A.; Tester, J. W.; Helling, R. K. Carbon Monoxide Oxidation in Supercritical Water: The Effects of Heat Transfer and the Water-Gas Shift Reaction on Observed Kinetics. Energy Fuels 1993, 6 (5), 586.
44. Xu, X.; Antal, M. J., Jr. Mechanism and Kinetics of the Auto-Catalytic Dehydration of t-Butanol in Near-Critical Water. Presented at AIChE Annual Meeting, Los Angeles, CA, Nov 17-22, 1991.