Direct observation of H2O2 during alcohol oxidation by O2 in supercritical water

Industrial and Engineering Chemistry Research

Volumn 37, Issue 5, 1998, Pages 1755-1760

  Croiset, Eric ^a   Rice, Steven F ^a  

^a SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHANOL; MATHEMATICAL MODELS; METHANOL; MOLECULAR VIBRATIONS; OXIDATION; OXYGEN; RAMAN SPECTROSCOPY; REACTION KINETICS; WATER;

SUPERCRITICAL WATER;

HYDROGEN PEROXIDE;

EID: 0032074133     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970711e     Document Type: Article

References (10)

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2. Brock, E. E.; Oshima, Y.; Savage, P. E.; Barker, J. R. Kinetics and Mechanism of Methanol Oxidation in Supercritical Water. J. Phys. Chem. 1996, 100, 15834.
3. Cozewith, C.; Busko, M. Design Correlations for Mixing Tees. Ind. Eng. Chem. Res. 1989, 28, 1521.
4. Croiset, E.; Rice, S. F.; Hanush, R. G. Hydrogen Peroxide Decomposition in Supercritical Water. AIChE J. 1997,43,2343.
5. Dagaut, P.; Cathonnet, M.; Boettner, J.-C. Chemical Kinetics Modeling of the Supercritical Water Oxidation of Methanol. J. Supercrit. Fluids 1996, 98, 33.
6. 2 Vapor. J. Raman Spectrosc. 1974, 2, 125.
7. Hanush, R. G.; Rice, S. F.; Hunter T. B. Operation and Performance of the Supercritical Fluids Reactor (SFR); Sandia National Laboratories [Technical Report] SAND96-8203; Sandia National Laboratories: Livermore, CA, 1995.
8. Hunter, T. B.; Rice, S. F.; Hanush, R. G. Raman Spectroscopic Measurement of Oxidation in Supercritical Water. 2. Conversion of Isopropyl Alcohol to Acetone. Ind. Eng. Chem. Res. 1996, 35, 3984.
9. Rice, S. F.; Hunter T. B.; Rydén Å. G.; Hanush R. G. Raman Spectroscopic Measurement of Oxidation in Supercritical Water. 1. Conversion of Methanol to Formaldehyde. Ind. Eng. Chem. Res. 1996, 35, 2161.
10. Schmitt, R. G.; Butler, P. B.; Bergan, N. E.; Pitz, W. J.; Westbrook, C. K. Destruction of Hazardous Waste in Supercritical Water. Part II: A Study of High-Pressure Methanol Oxidation Kinetics. Fall Meeting of the Western States Section/The Combustion Institute, Los Angeles, October, 1991; The Combustion Institute: Pittsburgh, PA, 1991.