Silicon compounds with strong intramolecular steric interactions, 71. Silylene reactions with buta-1,3-diynes: Cycloadditions, insertions, and rearrangements

European Journal of Inorganic Chemistry

Volumn , Issue 12, 1999, Pages 2301-2307

  Ostendorf, Detlev ^a   Kirmaier, Lars ^a   Saak, Wolfgang ^a   Marsmann, Heinrich ^b   Weidenbruch, Manfred ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b UNIVERSITY OF PADERBORN   (Germany)

Author keywords

Cycloadditions; Insertions; Multiple bonds; Silicon; Silylene

Indexed keywords

IRRADIATION; SILICON COMPOUNDS; X RAY CRYSTALLOGRAPHY;

CYCLOADDITIONS; DISILACYCLOBUTANE DERIVATIVES; INSERTION; MULTIPLE BONDS; SILYLENES; STERIC INTERACTIONS; TRISILANES;

PHOTOLYSIS;

SILANE DERIVATIVE; SILICON;

ARTICLE; CHEMICAL BOND; CONFORMATIONAL TRANSITION; CYCLIZATION; MOLECULAR INTERACTION; PHOTOLYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0032725695     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199912)1999:12<2301::aid-ejic2301>3.0.co;2-e     Document Type: Article

References (28)

1. Review: P. P. Gaspar, R. West, in: The Chemistry of Organic Silicon Compounds, Vol. II (Eds.: Z. Rappoport, Y. Apeloig), Wiley, Chichester, UK, 1998, p. 2463-2569.
2. Review: M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275-300.
3. A. Schäfer, M. Weidenbruch, K. Peters, H. G. von Schnering, Angew. Chem. 1984, 96, 311-312; Angew. Chem. Int. Ed. Engl. 1984, 23, 302-303.
4. A. Schäfer, M. Weidenbruch, K. Peters, H. G. von Schnering, Angew. Chem. 1984, 96, 311-312; Angew. Chem. Int. Ed. Engl. 1984, 23, 302-303.
5. P. Boudjouk, U. Samaraweera, R. Sooriyakumaran, J. Chrisciel, Angew. Chem. 1988, 100, 1406-1407; Angew. Chem. Int. Ed. Engl. 1988, 27, 1355-1356.
6. P. Boudjouk, U. Samaraweera, R. Sooriyakumaran, J. Chrisciel, Angew. Chem. 1988, 100, 1406-1407; Angew. Chem. Int. Ed. Engl. 1988, 27, 1355-1356.
7. M. J. Fink, M. J. Michalazyk, K. J. Haller, R. West, J. Michl, Organometallics 1984, 3, 793-800.
8. M. Weidenbruch, H. Piel, K. Peters, H. G. von Schnering, Organometallics 1994, 13, 3990-3994.
9. L. Kirmaier, M. Weidenbruch, H. Marsmann, K. Peters, H. G. von Schnering, Organometallics 1998, 17, 1237-1240.
10. W. S. Palmer, K. A. Woerpel, Organometallics 1997, 16, 4824-4827.
11. K. Peters, E.-M. Peters, D. Ostendorf, M. Weidenbruch, Z. Kristallogr. NCS, in press.
12. E. Lukevics, O. Pudova, R. Sturkovich, Molecular Structure of Organosilicon Compounds, Ellis Horwood, Chichester, UK, 1989.
13. A. Kunai, T. Mihara, Y. Matsuo, J. Oshita, A. Naka, M. Ishikawa, J. Organomet. Chem. 1997, 545-546, 611-613.
14. For an Si - Si-linked bis(silirene), see: W. Ando, T. Shiba, T. Hidaka, K. Morihashi, O. Kikuchi, J. Am. Chem. Soc. 1997, 119, 3629-3630.
15. A. Almenningen, O. Bastiansen, M. Traetterburg, Acta Chem. Scand 1958, 12, 1221-1225.
16. H. Watanabe, K. Takeuchi, N. Fukawa, M. Kato, M. Goto, Y. Naigai, Chem. Lett. 1987, 1341-1344.
17. A. J. Millevolte, D. R. Powell, S. G. Johnson, R. West, Organometallics 1992, 11, 1091-1095.
18. K. Peters, E.-M. Peters, L. Kirmaier, D. Ostendorf, M. Weidenbruch, Z. Kristallogr. NCS 1999, 214, 339-540.
19. T. Takahashi, Z. Z. Xi, Y. Obara, N. Suzuki, J. Am. Chem. Soc. 1995, 117, 2665-2666.
20. [18a] S. Pulst, P. Arndt, B. Heller, W. Baumann, R. Kempe, U. Rosenthal, Angew. Chem. 1996, 108, 1175-1178; Angew. Chem. Int. Ed. Engl. 1996, 35, 1112-1115.
21. [18a] S. Pulst, P. Arndt, B. Heller, W. Baumann, R. Kempe, U. Rosenthal, Angew. Chem. 1996, 108, 1175-1178; Angew. Chem. Int. Ed. Engl. 1996, 35, 1112-1115.
22. [18b] S. Pulst, F. G. Kirchbauer, B. Heller, W. Baumann, U. Rosenthal, Angew. Chem. 1998, 110, 2029-2031; Angew. Chem. Int. Ed. 1998, 37, 1925-1927.
23. [18b] S. Pulst, F. G. Kirchbauer, B. Heller, W. Baumann, U. Rosenthal, Angew. Chem. 1998, 110, 2029-2031; Angew. Chem. Int. Ed. 1998, 37, 1925-1927.
24. T. J. Barton, J. Lin, S. Ijadi-Maghsoodi, M. D. Power, X. Zhang, Z. Ma, H. Shimizu, M. S. Gordon, J. Am. Chem. Soc. 1995, 117, 11695-11703.
25. G. E. Miracle, J. L. Ball, D. R. Powell, R. West, J. Am. Chem. Soc. 1993, 115, 11598-11599.
26. M. Trommer, G. Miracle, B. E. Eichler, D. R. Powell, R. West, Organometallics 1997, 16, 5737-5747.
27. G. M. Sheldrick, SHELXL-93/97. Programs for Crystal Structure Refinement, Universität Göttingen, Germany, 1993/1997.
28. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-122 319 (12), CCDC-122 322 (15), CCDC-122 323 (18), CCDC-122 321 (trans-21), and CCDC-122 320 (cis-21). Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K. [Fax: (internat.) +44(0)1223/336093; E-mail: deposit@ccdc.cam.ac.uk].