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We thank one of the referees for this additional hint.
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.CCR species.). The irradiation of the silylalkynyl complex D in the presence of 2 or of E in the presence of 1 does not lead to C or 3. Therefore, a direct reaction of the postulated monomeric σ-alkynyltitanium(III) intermediates with the butadiynes in a Ti-C/C-C metathesis reaction can be ruled out here.
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