(6R,7R)-[4,5,6,7-2H4]-Palmitoate and (8S,9R)-[8,9-2H2]- L-erythro- sphinganine: Probes for the analysis of the stereochemical course of Δ6- desaturases from plants and insects

Synthesis

Volumn , Issue 12, 1999, Pages 2145-2150

  Thum, Oliver ^a   Hertweck, Christian ^a   Simon, Helmut ^b   Boland, Wilhelm ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ECOLOGY   (Germany)

^b Inst for Organ Chem and Biochem   (Germany)

Author keywords

Asymmetric reduction of (E) alk 2 enoates; Chirally deuterated palmitic acid; Chirally deuterated sphingosines; Cuprate mediated alkylation; Lipids; Oxidations; Wittig reactions

Indexed keywords

OXIDOREDUCTASE; PALMITIC ACID DERIVATIVE; SPHINGOLIPID;

ARTICLE; CATALYSIS; CHIRALITY; CLOSTRIDIUM BUTYRICUM; ENZYME MECHANISM; ENZYME SPECIFICITY; NONHUMAN; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0032715529     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-3630     Document Type: Article

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