vic-difluorination of fluoroalkenes with xenon difiuoride: The effect of fluorine substituents on the reaction of alkenes with xenon difluoride

European Journal of Organic Chemistry

Volumn , Issue 11, 1999, Pages 3151-3153

  Tamura, Masanori ^a   Quan, Heng Dao ^a   Sekiya, Akira ^a  

^a NATL INST OF MAT AND CHEM RES   (Japan)

Author keywords

Alkenes; Fluorine; Fluoroalkenes; Vic Difluorination; Xenon difluoride

Indexed keywords

ALKENE; CATION; FLUORIDE; UNCLASSIFIED DRUG; XENON; XENON DIFLUORIDE;

ARTICLE; CATALYST; FLUORINATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS;

EID: 0032698823     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0690(199911)1999:11<3151::aid-ejoc3151>3.0.co;2-f     Document Type: Article

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18. 4 afforded the corresponding product in 90% yield although the substrate is an alkyl-substituted fluoroalkene.[16] However, this result would appear to be very specific and seems to depend on the substrate - vic-difluorination of 1-fluorocyohexene under the same reaction conditions resulted in less than 30% yield according to our experiment.
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