Difluorination of alkenes with iodotoluene difluoride

Synlett

Volumn , Issue 5, 1998, Pages 495-496

  Hara, Shoji ^a   Nakahigashi, Jun ^a   Ishi i, Kenji ^a   Sawaguchi, Masaki ^a   Sakai, Hiroshi ^a   Fukuhara, Tsuyoshi ^a   Yoneda, Norihiko ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002858207     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-1714     Document Type: Article

References (18)

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7. 2 gas is necessary for its preparation.
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10. b) Hara, S.; Hatakeyama, T.; Chen, S.-Q.; Ishi-i, K.; Yoshida, M.; Sawaguchi, M.; Fukuhara, T.; Yoneda, N. J. Fluorine Chem., 1998, in press.
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16. 3N to 5 equiv. of anhydrous HF at -78°C under nitrogen. It is much easier to handle than HF itself, but for the prevention of any hazards, the use of rubber gloves is recommended.
17. 9
18. Hara, S.; Nakahigashi, J.; Ishi-i, K.; Fukuhara, T.; Yoneda, N. Tetrahedron Lett., 1998, in press.