Branched-chain functionalised carbohydrates via β-functionalised organolithium compounds

Tetrahedron Asymmetry

Volumn 9, Issue 22, 1998, Pages 3939-3943

  Soler, Tatiana ^a   Bachki, Abderrazak ^a   Falvello, Larry R ^b   Foubelo, Francisco ^a   Yus, Miguel ^a  

^a UNIVERSITY OF ALICANTE   (Spain)

^b UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOHYDRATE DERIVATIVE; EPOXIDE; ORGANOLITHIUM COMPOUND; WATER;

ARTICLE; CARBOHYDRATE ANALYSIS; DIASTEREOISOMER; ENANTIOMER; HYDROLYSIS; PRIORITY JOURNAL;

EID: 0032573614     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00411-X     Document Type: Article

References (32)

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25. 2; c 1.08). (equation presented)
26. o). The enantiomorph was fixed according to the known stereochemistry of four of the chiral centres in the molecule, (b) Data were processed on an AlphaStation 200 4/166 (OpenVMS Alpha V6.2), using the program XCAD4B (K. Harms, University of Marburg) and the commercial package SHELXTL-PLUS Release 5.05/V. © 1996 Siemens Analytical X-Ray Instruments, Inc., Madison, WI. (c) SHELXS-97: Fortran program for crystal structure solution. © 1997 G. M. Sheldrick. (d) SHELXL-97: Fortran program for crystal structure solution. © 1997 G. M. Sheldrick.
27. 2; c 1.2).
28. 2; c 1.26).
29. 2; c 1.10).
30. 15 takes place to the convex β-position by the preferential control due to the rigid bicyclic structure. See, for instance: (a) Peterson, M. A.; Mitchell, J. R. J. Org. Chem. 1997, 62, 8237. (b) Yamauchi, N.; Kishida, M.; Sawada, K.; Ohashi, Y.; Eguchi, T.; Kakinura, K. Chem. Lett. 1998, 475. (c) See also Ref. 4.
31. 15 takes place to the convex β-position by the preferential control due to the rigid bicyclic structure. See, for instance: (a) Peterson, M. A.; Mitchell, J. R. J. Org. Chem. 1997, 62, 8237. (b) Yamauchi, N.; Kishida, M.; Sawada, K.; Ohashi, Y.; Eguchi, T.; Kakinura, K. Chem. Lett. 1998, 475. (c) See also Ref. 4.
32. 15 takes place to the convex β-position by the preferential control due to the rigid bicyclic structure. See, for instance: (a) Peterson, M. A.; Mitchell, J. R. J. Org. Chem. 1997, 62, 8237. (b) Yamauchi, N.; Kishida, M.; Sawada, K.; Ohashi, Y.; Eguchi, T.; Kakinura, K. Chem. Lett. 1998, 475. (c) See also Ref. 4.